Kinetics of Selective Trimerization of Ethylene to 1-Hexene over Chromium-Based Catalysts.
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| Title: | Kinetics of Selective Trimerization of Ethylene to 1-Hexene over Chromium-Based Catalysts. |
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| Authors: | Faingol'd, E. E.1 (AUTHOR) fevgeny@mail.ru, Lashmanov, N. N.1 (AUTHOR), Saratovskikh, S. L.1 (AUTHOR), Kulchakovsky, P. I.2,3 (AUTHOR), Lenev, D. A.2 (AUTHOR), Shamukaev, V. A.2 (AUTHOR), Sedov, I. V.1,4 (AUTHOR) |
| Source: | Petroleum Chemistry. Dec2023, Vol. 63 Issue 11, p1335-1352. 18p. |
| Subjects: | Trimerization, Ethylene, Chromium catalysts, Catalysts, Catalysis |
| Abstract: | This review provides an analysis of prior research on the kinetics of the trimerization of ethylene to 1-hexene over existing chromium-based catalytic systems. It discusses the known mechanisms and reaction steps for the formation of 1-hexene as well as olefin by-products. The effects of catalytic system composition, temperature, pressure, reaction time, and the presence of hydrogen on the kinetics of 1-hexene formation are also touched upon. The kinetic models of ethylene trimerization to 1-hexene known from published literature are presented. [ABSTRACT FROM AUTHOR] |
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| Database: | Engineering Source |
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| Abstract: | This review provides an analysis of prior research on the kinetics of the trimerization of ethylene to 1-hexene over existing chromium-based catalytic systems. It discusses the known mechanisms and reaction steps for the formation of 1-hexene as well as olefin by-products. The effects of catalytic system composition, temperature, pressure, reaction time, and the presence of hydrogen on the kinetics of 1-hexene formation are also touched upon. The kinetic models of ethylene trimerization to 1-hexene known from published literature are presented. [ABSTRACT FROM AUTHOR] |
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| ISSN: | 09655441 |
| DOI: | 10.1134/S0965544123110026 |
