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Kinetics of Selective Trimerization of Ethylene to 1-Hexene over Chromium-Based Catalysts.

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Title: Kinetics of Selective Trimerization of Ethylene to 1-Hexene over Chromium-Based Catalysts.
Authors: Faingol'd, E. E.1 (AUTHOR) fevgeny@mail.ru, Lashmanov, N. N.1 (AUTHOR), Saratovskikh, S. L.1 (AUTHOR), Kulchakovsky, P. I.2,3 (AUTHOR), Lenev, D. A.2 (AUTHOR), Shamukaev, V. A.2 (AUTHOR), Sedov, I. V.1,4 (AUTHOR)
Source: Petroleum Chemistry. Dec2023, Vol. 63 Issue 11, p1335-1352. 18p.
Subjects: Trimerization, Ethylene, Chromium catalysts, Catalysts, Catalysis
Abstract: This review provides an analysis of prior research on the kinetics of the trimerization of ethylene to 1-hexene over existing chromium-based catalytic systems. It discusses the known mechanisms and reaction steps for the formation of 1-hexene as well as olefin by-products. The effects of catalytic system composition, temperature, pressure, reaction time, and the presence of hydrogen on the kinetics of 1-hexene formation are also touched upon. The kinetic models of ethylene trimerization to 1-hexene known from published literature are presented. [ABSTRACT FROM AUTHOR]
Copyright of Petroleum Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Kinetics of Selective Trimerization of Ethylene to 1-Hexene over Chromium-Based Catalysts.
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  Data: <searchLink fieldCode="JN" term="%22Petroleum+Chemistry%22">Petroleum Chemistry</searchLink>. Dec2023, Vol. 63 Issue 11, p1335-1352. 18p.
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  Data: This review provides an analysis of prior research on the kinetics of the trimerization of ethylene to 1-hexene over existing chromium-based catalytic systems. It discusses the known mechanisms and reaction steps for the formation of 1-hexene as well as olefin by-products. The effects of catalytic system composition, temperature, pressure, reaction time, and the presence of hydrogen on the kinetics of 1-hexene formation are also touched upon. The kinetic models of ethylene trimerization to 1-hexene known from published literature are presented. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Petroleum Chemistry is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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