Selection of simulants for separating radionuclides of transplutonium and rare-earth elements via displacement complexing chromatography with DTPA-based eluents.

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Title: Selection of simulants for separating radionuclides of transplutonium and rare-earth elements via displacement complexing chromatography with DTPA-based eluents.
Authors: Kharitonov, Oleg V.1 (AUTHOR), Firsova, Lubov A.1 (AUTHOR), Fadeeva, Anna V.1 (AUTHOR), Kozlitin, Evgeny A.1 (AUTHOR) evgeny_kozlitin@mail.ru
Source: Journal of Radioanalytical & Nuclear Chemistry. May2024, Vol. 333 Issue 5, p2433-2437. 5p.
Subjects: Transplutonium elements, Rare earth metals, Radioisotopes, Terbium, Curium, Americium, Rare earth oxides
Abstract: The paper presents data on selecting curium and americium simulants for the lab-scale development of a displacement complexing chromatography-based separation technique. Being eluted with the eluents based on DTPA and a mixture of DTPA and citric acid, the rare earth element holmium behaves exactly as curium and terbium—as americium. Conversely, the tracer additives of transplutonium radionuclides are a perfect option for rare earth separation studies. [ABSTRACT FROM AUTHOR]
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Abstract:The paper presents data on selecting curium and americium simulants for the lab-scale development of a displacement complexing chromatography-based separation technique. Being eluted with the eluents based on DTPA and a mixture of DTPA and citric acid, the rare earth element holmium behaves exactly as curium and terbium—as americium. Conversely, the tracer additives of transplutonium radionuclides are a perfect option for rare earth separation studies. [ABSTRACT FROM AUTHOR]
ISSN:02365731
DOI:10.1007/s10967-024-09477-8