A facile in-situ strategy to fabricate lightweight carbon fiber/silicone-phenolic aerogel composites with superior toughness and ablation performance.

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Title: A facile in-situ strategy to fabricate lightweight carbon fiber/silicone-phenolic aerogel composites with superior toughness and ablation performance.
Authors: Wang, Wenkai1 (AUTHOR), Xu, Wenjie1 (AUTHOR), Jia, Xianfeng2 (AUTHOR), Zhang, Fuhang3 (AUTHOR), Cao, Yinping3 (AUTHOR), Ma, Cheng1 (AUTHOR), Wang, Jitong1 (AUTHOR), Qiao, Wenming1 (AUTHOR) qiaowm@ecust.edu.cn, Ling, Licheng1 (AUTHOR)
Source: Journal of Materials Science. Oct2024, Vol. 59 Issue 39, p18488-18498. 11p.
Subjects: Flexural modulus, Ablative materials, Astronautics, Thermal conductivity, Thermal stability
Abstract: The development of lightweight carbon fiber/phenolic ablator plays a vital role in advancements of space technology. However, the complex fabrication process and inherent brittleness of ablators impede its further progress. Herein, we fabricated a high-performance carbon fiber/silicone-phenolic aerogel (CFSP) composite through a facile in-situ strategy, which exhibits lightweight nature (0.25–0.28 g/cm3), low thermal conductivity (0.054–0.056 W/(m·K)) and thermal stability. Meanwhile, the as-designed composites effectively addressed the disadvantage of brittleness that exhibited a fracture strain of 34.32% and a flexural modulus of 4.07 MPa, which was a significant improvement compared with the toughness of the unmodified composite (15.60%, 21.44 MPa, respectively). Notably, in the oxyacetylene test, the linear ablation rates show a great decline from 0.381 mm/s to 0.227 mm/s with the increase in silicone contents. Therefore, the CFSP composite is a competitive candidate for the thermal protection material of the next generation of hypersonic vehicles. [ABSTRACT FROM AUTHOR]
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Abstract:The development of lightweight carbon fiber/phenolic ablator plays a vital role in advancements of space technology. However, the complex fabrication process and inherent brittleness of ablators impede its further progress. Herein, we fabricated a high-performance carbon fiber/silicone-phenolic aerogel (CFSP) composite through a facile in-situ strategy, which exhibits lightweight nature (0.25–0.28 g/cm3), low thermal conductivity (0.054–0.056 W/(m·K)) and thermal stability. Meanwhile, the as-designed composites effectively addressed the disadvantage of brittleness that exhibited a fracture strain of 34.32% and a flexural modulus of 4.07 MPa, which was a significant improvement compared with the toughness of the unmodified composite (15.60%, 21.44 MPa, respectively). Notably, in the oxyacetylene test, the linear ablation rates show a great decline from 0.381 mm/s to 0.227 mm/s with the increase in silicone contents. Therefore, the CFSP composite is a competitive candidate for the thermal protection material of the next generation of hypersonic vehicles. [ABSTRACT FROM AUTHOR]
ISSN:00222461
DOI:10.1007/s10853-024-10282-7