Bibliographic Details
| Title: |
A mixed isocyanide Mn(I) complex and its reduction to a metallate. |
| Authors: |
Claude, Guilhem1 (AUTHOR), Ellwanger, Mathias A.1 (AUTHOR), Grippo, Adam2 (AUTHOR), Hernandez, Ritchie2 (AUTHOR), Figueroa, Joshua R.2 (AUTHOR) jsfig@ucsd.edu, Abram, Ulrich1 (AUTHOR) ulrich.abram@fu-berlin.de |
| Source: |
Dalton Transactions: An International Journal of Inorganic Chemistry. 4/21/2025, Vol. 54 Issue 15, p6025-6028. 4p. |
| Subjects: |
Isocyanides, Heteroleptic compounds, Metal complexes, Ligand exchange reactions, Chemical reduction |
| Abstract: |
A stepwise ligand exchange starting from [Mn(CO)5Br] allows the synthesis of the heteroleptic isocyanide manganese(I) complex mer,trans-[Mn(CNp-FArDArF2)3(CNtBu)2Br] (DArF = 3,5-(CF3)2C6H3, tBu = tert-butyl). Subsequent reduction gave the first heteroleptic isocyanide manganese(−1) complex, [K(18-crown-6)][Mn(CNp-FArDArF2)3(CNtBu)2], exhibiting a five-coordinate, trigonal bipyramidal coordination sphere. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
