Minimizing Anomalous Electrodeposition of Fe20Ni80 Alloy Thin Films: Effect on Structural and Magnetic Properties.

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Title: Minimizing Anomalous Electrodeposition of Fe20Ni80 Alloy Thin Films: Effect on Structural and Magnetic Properties.
Authors: Dev, Kapil1 (AUTHOR) devkapil108@gmail.com, Shweta1 (AUTHOR), Annapoorni, S.1 (AUTHOR)
Source: Integrated Ferroelectrics. 2025, Vol. 241 Issue 1-3, p92-100. 9p.
Subjects: Substrates (Materials science), Magnetic films, Boric acid, Electrolyte solutions, Alloy plating
Abstract: This study explores the controlled electrochemical deposition of Fe20Ni80 alloy thin films by varying boric acid concentrations in the electrolyte solution to prevent anomalous electrodeposition of iron and attain desired film characteristics. Cyclic voltammetry plots confirm an increase in reduction current density with higher boric acid concentrations. Successful deposition of desired Fe20Ni80 alloy composition films on ITO/glass substrate was achieved with electrolyte solution having 0.5 M boric acid solution. Morphological and magnetic investigation reveals that films produced with higher boric acid concentrations exhibit more uniform deposition with finer particle size, desired alloy composition and superior magnetic properties. Bulk hysteresis measurements confirm soft ferromagnetic behavior with low coercivity (Hc∼ 40 Oe) and high in-plane remanence ratio indicating an in-plane easy axis. The magnetic behavior of the films can be correlated with the deposited alloy composition. The surface hysteresis obtained from the Longitudinal Magneto Optic Kerr Effect supports the bulk hysteresis behavior. By utilizing appropriate boric acid concentrations in electrolytes, the electrodeposited Fe–Ni film's structural and magnetic properties could be finely tuned for their potential technological applications. [ABSTRACT FROM AUTHOR]
Copyright of Integrated Ferroelectrics is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: <searchLink fieldCode="JN" term="%22Integrated+Ferroelectrics%22">Integrated Ferroelectrics</searchLink>. 2025, Vol. 241 Issue 1-3, p92-100. 9p.
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  Data: <searchLink fieldCode="DE" term="%22Substrates+%28Materials+science%29%22">Substrates (Materials science)</searchLink><br /><searchLink fieldCode="DE" term="%22Magnetic+films%22">Magnetic films</searchLink><br /><searchLink fieldCode="DE" term="%22Boric+acid%22">Boric acid</searchLink><br /><searchLink fieldCode="DE" term="%22Electrolyte+solutions%22">Electrolyte solutions</searchLink><br /><searchLink fieldCode="DE" term="%22Alloy+plating%22">Alloy plating</searchLink>
– Name: Abstract
  Label: Abstract
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  Data: This study explores the controlled electrochemical deposition of Fe20Ni80 alloy thin films by varying boric acid concentrations in the electrolyte solution to prevent anomalous electrodeposition of iron and attain desired film characteristics. Cyclic voltammetry plots confirm an increase in reduction current density with higher boric acid concentrations. Successful deposition of desired Fe20Ni80 alloy composition films on ITO/glass substrate was achieved with electrolyte solution having 0.5 M boric acid solution. Morphological and magnetic investigation reveals that films produced with higher boric acid concentrations exhibit more uniform deposition with finer particle size, desired alloy composition and superior magnetic properties. Bulk hysteresis measurements confirm soft ferromagnetic behavior with low coercivity (Hc∼ 40 Oe) and high in-plane remanence ratio indicating an in-plane easy axis. The magnetic behavior of the films can be correlated with the deposited alloy composition. The surface hysteresis obtained from the Longitudinal Magneto Optic Kerr Effect supports the bulk hysteresis behavior. By utilizing appropriate boric acid concentrations in electrolytes, the electrodeposited Fe–Ni film's structural and magnetic properties could be finely tuned for their potential technological applications. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Integrated Ferroelectrics is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1080/10584587.2025.2482414
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      – Code: eng
        Text: English
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        PageCount: 9
        StartPage: 92
    Subjects:
      – SubjectFull: Substrates (Materials science)
        Type: general
      – SubjectFull: Magnetic films
        Type: general
      – SubjectFull: Boric acid
        Type: general
      – SubjectFull: Electrolyte solutions
        Type: general
      – SubjectFull: Alloy plating
        Type: general
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      – TitleFull: Minimizing Anomalous Electrodeposition of Fe20Ni80 Alloy Thin Films: Effect on Structural and Magnetic Properties.
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            NameFull: Dev, Kapil
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            NameFull: Annapoorni, S.
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              M: 01
              Text: 2025
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              Y: 2025
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            – TitleFull: Integrated Ferroelectrics
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