Structural and Liberation Effect of Vanadium Titano-Magnetite by Microwave Pretreatment.

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Title: Structural and Liberation Effect of Vanadium Titano-Magnetite by Microwave Pretreatment.
Authors: Wang, Junpeng1 (AUTHOR) junp_wang@yeah.net, Liu, Bo1 (AUTHOR), Zhang, Yuyuan1 (AUTHOR), Jiang, Tao2 (AUTHOR)
Source: JOM: The Journal of The Minerals, Metals & Materials Society (TMS). Jul2025, Vol. 77 Issue 7, p5283-5292. 10p.
Subjects: Microwave heating, Microhardness testing, Crystal grain boundaries, Mineral analysis, Scanning electron microscopy
Abstract: This study explored the impact of microwave pretreatment on the structural and liberation characteristics of vanadium titano-magnetite (VTM). Various methods such as x-ray diffraction, scanning electron microscopy, micro-hardness testing, particle size analysis, and mineral liberation analysis were utilized. Results indicated that microwave treatment improved the crystallization of titanomagnetite and ilmenite and generated numerous micro-cracks on the ore surface because of the selective heating by microwaves and differential expansion among minerals. This treatment also reduced the micro-hardness, particularly at grain boundaries, with a notable decrease of 78.09% at the grain boundary when treated at 4 kW for 150 s followed by water quenching. Additionally, the liberation degree of the grinding products from microwave-treated ore was superior to that of untreated ore, with increases of 4.92% for titanomagnetite and 8.13% for ilmenite when the grinding products with a particle size of − 0.075 mm accounted for 35%. These findings suggest that microwave pretreatment enhances the selective grinding effect and promotes detachment dissociation of grinding products. [ABSTRACT FROM AUTHOR]
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Abstract:This study explored the impact of microwave pretreatment on the structural and liberation characteristics of vanadium titano-magnetite (VTM). Various methods such as x-ray diffraction, scanning electron microscopy, micro-hardness testing, particle size analysis, and mineral liberation analysis were utilized. Results indicated that microwave treatment improved the crystallization of titanomagnetite and ilmenite and generated numerous micro-cracks on the ore surface because of the selective heating by microwaves and differential expansion among minerals. This treatment also reduced the micro-hardness, particularly at grain boundaries, with a notable decrease of 78.09% at the grain boundary when treated at 4 kW for 150 s followed by water quenching. Additionally, the liberation degree of the grinding products from microwave-treated ore was superior to that of untreated ore, with increases of 4.92% for titanomagnetite and 8.13% for ilmenite when the grinding products with a particle size of − 0.075 mm accounted for 35%. These findings suggest that microwave pretreatment enhances the selective grinding effect and promotes detachment dissociation of grinding products. [ABSTRACT FROM AUTHOR]
ISSN:10474838
DOI:10.1007/s11837-025-07143-2