Demonstration of ferroelectricity in Zn1-xMgxO thin films over a wide Mg concentration range.

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Title: Demonstration of ferroelectricity in Zn1-xMgxO thin films over a wide Mg concentration range.
Authors: Zhao, Wenjin1 (AUTHOR), Zhou, Dayu1 (AUTHOR) zhoudayu@dlut.edu.cn, Sui, Jinyang1 (AUTHOR), Tong, Yi2 (AUTHOR), Wang, Xinpeng2 (AUTHOR), Zhu, Longxiao1 (AUTHOR)
Source: Journal of Materials Science: Materials in Electronics. Jun2025, Vol. 36 Issue 18, p1-9. 9p.
Abstract: Zn1-xMgxO thin films with a Mg content ranging from 35 to 53 at% were prepared by dual-target reactive magnetron co-sputtering at room temperature. X-ray diffractions show highly (0002)-preferred orientation growth of the wurtzite-structured films and the appearance of the rock-salt phase in films with the Mg concentration higher than 43 at%. The polarization and transient current hysteresis curve measurements confirm that the ferroelectricity can be achieved not only in single wurtzite-structured films, but also surprisingly in films co-existing with wurtzite and rock-salt phases. The results contribute significant progress in understanding and further optimizing the ferroelectric property of wurtzite-structured materials, while achieving a broader ferroelectric composition range is also more advantageous for device applications. [ABSTRACT FROM AUTHOR]
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Abstract:Zn1-xMgxO thin films with a Mg content ranging from 35 to 53 at% were prepared by dual-target reactive magnetron co-sputtering at room temperature. X-ray diffractions show highly (0002)-preferred orientation growth of the wurtzite-structured films and the appearance of the rock-salt phase in films with the Mg concentration higher than 43 at%. The polarization and transient current hysteresis curve measurements confirm that the ferroelectricity can be achieved not only in single wurtzite-structured films, but also surprisingly in films co-existing with wurtzite and rock-salt phases. The results contribute significant progress in understanding and further optimizing the ferroelectric property of wurtzite-structured materials, while achieving a broader ferroelectric composition range is also more advantageous for device applications. [ABSTRACT FROM AUTHOR]
ISSN:09574522
DOI:10.1007/s10854-025-15197-w