Bibliographic Details
| Title: |
Cooperative enhancement of redox catalysis in divanadium complexes binucleated by 1,8-naphthyridine-2,7-dicarboxylate. |
| Authors: |
Simran, Simran1, Tansky, Maxym2, Trabulsi, Seth3, Liangzi Deng3, Ching-Wu Chu3, Ozarowski, Andrew4, Comito, Robert J.1 rjcomito@central.uh.edu |
| Source: |
Dalton Transactions: An International Journal of Inorganic Chemistry. 11/7/2025, Vol. 54 Issue 41, p15400-15405. 6p. |
| Subjects: |
Vanadium catalysts, Catalysis, Magnetometers, Oxidation-reduction reaction, Density functional theory, Vanadium compounds, X-ray crystallography |
| Abstract: |
We report discrete divanadium complexes of 1,8-naphthyridine-2,7-dicarboxylate, characterized by SCXRD, DFT modelling, and magnetometry. One complex shows significantly greater activity in the aerobic cleavage of diols and a lignin model compound than its monometallic analogs. Mechanistic experiments and a substrate-bound complex provide insight into cooperativity in vanadium redox catalysis. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
