Synthesis and holographic storage properties of polymethacrylates with azothiazole chromophore in the side chain.

Saved in:
Bibliographic Details
Title: Synthesis and holographic storage properties of polymethacrylates with azothiazole chromophore in the side chain.
Authors: Nadtoka, Oksana1 (AUTHOR) oksananadtoka@ukr.net, Smokal, Vitalii1 (AUTHOR), Studzinsky, Sergey1 (AUTHOR), Fanasova, Anna1 (AUTHOR)
Source: Molecular Crystals & Liquid Crystals. 2025, Vol. 769 Issue 15-18, p1461-1470. 10p.
Subjects: Polymethacrylates, Holography, Diffraction gratings, Azobenzene, Optical devices, Thin films, Copolymerization, Chromophores
Abstract: Polymers containing azothiazole chromophores in their side chain were synthesized by radical copolymerization with methyl methacrylate and characterized by 1H NMR, FT-IR, and UV–Vis spectroscopy. Also, its holographic properties were investigated in thin-film copolymers samples. A comparison is made with azobenzene polymers to study the effect of chromophore structure on optical storage properties. Thin films of polyesters were prepared and diffraction grating was formed on their surface. These polyesters exhibited diffraction patterns owing to the reorientation of azo chromophores by the cis-trans isomerization process. This reorientation results in a change in the polymer refractive index, which can be used to fabricate several optical devices. [ABSTRACT FROM AUTHOR]
Copyright of Molecular Crystals & Liquid Crystals is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
Description
Abstract:Polymers containing azothiazole chromophores in their side chain were synthesized by radical copolymerization with methyl methacrylate and characterized by 1H NMR, FT-IR, and UV–Vis spectroscopy. Also, its holographic properties were investigated in thin-film copolymers samples. A comparison is made with azobenzene polymers to study the effect of chromophore structure on optical storage properties. Thin films of polyesters were prepared and diffraction grating was formed on their surface. These polyesters exhibited diffraction patterns owing to the reorientation of azo chromophores by the cis-trans isomerization process. This reorientation results in a change in the polymer refractive index, which can be used to fabricate several optical devices. [ABSTRACT FROM AUTHOR]
ISSN:15421406
DOI:10.1080/15421406.2025.2528277