Durable and Robust Janus Membranes with Asymmetric Wettability Based on Poly (Vinylidene Fluoride)/Polyvinyl Alcohol for Oil–Water Separation.
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| Title: | Durable and Robust Janus Membranes with Asymmetric Wettability Based on Poly (Vinylidene Fluoride)/Polyvinyl Alcohol for Oil–Water Separation. |
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| Authors: | Chang, Yawen1 (AUTHOR), Sun, Ruihong1 (AUTHOR), Liu, Fujuan (AUTHOR) liufujuan@suda.edu.cn |
| Source: | Materials (1996-1944). Jan2026, Vol. 19 Issue 2, p363. 14p. |
| Subjects: | Oil separators, Polymeric membranes, Electrospinning, Wetting, Extraction (Chemistry), Mechanical behavior of materials, Polymers, Industrial wastes |
| Abstract: | With the acceleration of industrialization, the problems of water resource pollution and shortage caused by oil spills and industrial wastewater discharge have become increasingly severe, posing a major threat to ecological sustainable development. Therefore, efficient oil–water separation technology has become a key breakthrough to alleviate this crisis. In this study, Janus membranes with asymmetric wettability were prepared by layer-by-layer electrospinning. The influence of the thickness ratio between the hydrophobic layer and the hydrophilic layer on the mechanical properties, separation flux, and oil–water mixture efficiency of the Janus membranes was examined, and an optimized membrane configuration was determined: the optimal thickness ratio between hydrophobic and hydrophilic layers was 4:6. Under these conditions, the fracture stress of the fiber membranes reached 99% MPa, the fracture strain was 55.63 ± 4.77%, the separation flux values were 1888.22 and 1042.66 L m−2 h−1 for the oil–water mixture and water-in-oil emulsion, respectively, with the separation efficiencies all exceeding 99%. After 50 cycles of separation for two different oil-in-water emulsions, the separation flux and separation efficiency of the optimal sample remained relatively stable, demonstrating strong practicability. In general, the Janus fiber membranes met the expected requirements, laying a good foundation for future applications in oil–water separation, floating oil collection in water, and other fields. [ABSTRACT FROM AUTHOR] |
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| Database: | Engineering Source |
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| Abstract: | With the acceleration of industrialization, the problems of water resource pollution and shortage caused by oil spills and industrial wastewater discharge have become increasingly severe, posing a major threat to ecological sustainable development. Therefore, efficient oil–water separation technology has become a key breakthrough to alleviate this crisis. In this study, Janus membranes with asymmetric wettability were prepared by layer-by-layer electrospinning. The influence of the thickness ratio between the hydrophobic layer and the hydrophilic layer on the mechanical properties, separation flux, and oil–water mixture efficiency of the Janus membranes was examined, and an optimized membrane configuration was determined: the optimal thickness ratio between hydrophobic and hydrophilic layers was 4:6. Under these conditions, the fracture stress of the fiber membranes reached 99% MPa, the fracture strain was 55.63 ± 4.77%, the separation flux values were 1888.22 and 1042.66 L m−2 h−1 for the oil–water mixture and water-in-oil emulsion, respectively, with the separation efficiencies all exceeding 99%. After 50 cycles of separation for two different oil-in-water emulsions, the separation flux and separation efficiency of the optimal sample remained relatively stable, demonstrating strong practicability. In general, the Janus fiber membranes met the expected requirements, laying a good foundation for future applications in oil–water separation, floating oil collection in water, and other fields. [ABSTRACT FROM AUTHOR] |
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| ISSN: | 19961944 |
| DOI: | 10.3390/ma19020363 |
