Suprafacial and antarafacial paths for the thermal vinylcyclopropane-to-cyclopentene...

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Bibliographic Details
Title: Suprafacial and antarafacial paths for the thermal vinylcyclopropane-to-cyclopentene...
Authors: Baldwin, John E., Burrell, Richard C.
Source: Journal of Organic Chemistry. 05/14/99, Vol. 64 Issue 10, p3567. 5p. 10 Diagrams, 1 Graph.
Subjects: Cyclopropane, Heptane, Isomerization
Abstract: Explores the suprafacial and antarafacial paths for the thermal vinylcyclopropane-to-cyclopentene rearrangements of 1-ethenylbicyclo[4.1.0]heptane to bicyclo[4.3.0]on-1(9)-ene. Gas phase thermal rearrangement of 1-ethenylbicyclo[4.1.0]heptane; Isomerization of vinylcyclopropane to the corresponding cyclopentene; Conformational isomerization.
Database: Engineering Source
Description
Abstract:Explores the suprafacial and antarafacial paths for the thermal vinylcyclopropane-to-cyclopentene rearrangements of 1-ethenylbicyclo[4.1.0]heptane to bicyclo[4.3.0]on-1(9)-ene. Gas phase thermal rearrangement of 1-ethenylbicyclo[4.1.0]heptane; Isomerization of vinylcyclopropane to the corresponding cyclopentene; Conformational isomerization.
ISSN:00223263
DOI:10.1021/jo9824091