加氢裂化双功能分子筛催化剂研究进展.

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Bibliographic Details
Title: 加氢裂化双功能分子筛催化剂研究进展.
Alternate Title: Research progress of bifunctional zeolite catalysts for hydrocracking.
Authors: 范文轩1 fanwx3@cnooc.com.cn, 李永恒1, 宋宇1 songyu8@cnooc.com.cn, 韩龙年1, 方友2, 郑港西2, 张海洪1, 辛靖1
Source: Chemical Engineering of Oil & Gas / Shi You Yu Tian Ran Qi Hua Gong. Feb2026, Vol. 55 Issue 1, p21-27. 7p.
Subjects: Hydrocracking, Zeolite catalysts, Petroleum refining, Reaction mechanisms (Chemistry), Catalysts, Catalyst synthesis
Abstract (English): Hydrocracking technology plays a critical role in deep processing of heavy oils, optimizing product structures, and advancing refinery-to-chemical transitions in petrochemical industries. This review systematically summarized the reaction mechanisms of hydrocracking technology and design strategies for bifunctional zeolite catalysts. The reaction pathways of long-chain alkanes, cycloalkanes, and aromatic hydrocarbons in hydrocracking were discussed, and the effects of bifunctional synergy between metals and zeolite acidity on carbocation formation, cracking, and product distributions were analyzed. The synthesis progress of hydrocracking catalysts was discussed through several aspects including metal-acid site synergy, structural regulation of supports, and heteroatom modification. In view of the challenges faced by the development of hydrocracking catalyst, this review proposes potential research directions for the future, aiming to provide theoretical references for the development of hydrocracking catalyst, and facilitate the transition of refineries toward high-value-added chemical production. [ABSTRACT FROM AUTHOR]
Abstract (Chinese): 加氢裂化技术在炼化企业重油深度加工、产品结构调整及炼油向化工转型中发挥着重要的作用。系统地综述了 加氢裂化技术的反应机理与双功能分子筛催化剂的设计策略, 探讨了长链烷烃、环烷烃及芳烃的加氢裂化反应路径, 分析 了金属与分子筛酸性双功能协同作用对碳正离子生成、裂解及产物分布的影响。从金属−酸中心协同、载体结构调控及杂 原子改性等方面介绍了加氢裂化催化剂的合成进展。针对加氢裂化催化剂发展所面临的挑战, 提出了未来可能的研究方 向建议, 旨在为加氢裂化催化剂的开发提供理论参考, 助力炼厂向生产高附加值化工产品转型。 [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
Description
Abstract:Hydrocracking technology plays a critical role in deep processing of heavy oils, optimizing product structures, and advancing refinery-to-chemical transitions in petrochemical industries. This review systematically summarized the reaction mechanisms of hydrocracking technology and design strategies for bifunctional zeolite catalysts. The reaction pathways of long-chain alkanes, cycloalkanes, and aromatic hydrocarbons in hydrocracking were discussed, and the effects of bifunctional synergy between metals and zeolite acidity on carbocation formation, cracking, and product distributions were analyzed. The synthesis progress of hydrocracking catalysts was discussed through several aspects including metal-acid site synergy, structural regulation of supports, and heteroatom modification. In view of the challenges faced by the development of hydrocracking catalyst, this review proposes potential research directions for the future, aiming to provide theoretical references for the development of hydrocracking catalyst, and facilitate the transition of refineries toward high-value-added chemical production. [ABSTRACT FROM AUTHOR]
ISSN:10073426
DOI:10.3969/j.issn.1007-3426.2026.01.003