Ultrafine-Grained Al/Al2Cu Composite Formation via Friction Stir Processing of Cold-Sprayed Coatings.

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Title: Ultrafine-Grained Al/Al2Cu Composite Formation via Friction Stir Processing of Cold-Sprayed Coatings.
Authors: Rizvi, Syed Muhammad Mujtaba1 (AUTHOR), Uddin, Md Jasim2 (AUTHOR), McRobie, Chris1 (AUTHOR), Hartmann, Josephine1 (AUTHOR), Malakar, Aniruddha2 (AUTHOR), Yano, Kayla3 (AUTHOR), Barton, Dallin3 (AUTHOR), Tsai, Fu-Yun2 (AUTHOR), Laggner, Florian1 (AUTHOR), Gwalani, Bharat2 (AUTHOR) bgwalan@ncsu.edu, Kautz, Elizabeth1,3 (AUTHOR) ekautz@ncsu.edu
Source: JOM: The Journal of The Minerals, Metals & Materials Society (TMS). Jun2026, Vol. 78 Issue 6, p5357-5368. 12p.
Subjects: Aluminum alloys, Solid-state phase transformations, Microstructure, Material plasticity, Surface coatings, Nanocomposite materials, Mechanical behavior of materials
Abstract: We demonstrate a shear-deformation-driven, solid-state phase transformation pathway for the formation of an ultrafine-grained Al/Al 2 Cu composite via friction stir processing of a Cu cold-sprayed coating on an AA6061 aluminum substrate. This approach leverages the severe plastic deformation and high strain-rate environment inherent to friction stir processing to drive localized interdiffusion and solid-state reactions between the Cu coating and the Al alloy substrate. The processed surface exhibits a significant increase in hardness (≈ 250 HV), compared to both the AA6061 substrate (≈ 100 HV) and the as-deposited Cu coating (≈ 132 HV); these measured hardness values represent an increase of 1.8-times and 2.4-times relative to the Cu CS coating and AA6061 substrate, respectively. This hardness enhancement is attributed to the uniform distribution of fine-grained Al 2 Cu reinforcement within an Al(Cu) matrix, as confirmed by transmission electron microscopy and atom probe tomography. Unlike conventional precipitation hardening, here, discrete Al 2 Cu grains are directly formed and dispersed among Al grains, resulting in a hetero-grained microstructure that transitions into a single-phase matrix below the processed zone. Our results demonstrate the potential of integrating solid-state deposition with high-speed mechanical mixing to generate unique, non-equilibrium microstructures that bypass equilibrium melting constraints and exceed the performance of conventional thermomechanical processing routes. [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
Description
Abstract:We demonstrate a shear-deformation-driven, solid-state phase transformation pathway for the formation of an ultrafine-grained Al/Al 2 Cu composite via friction stir processing of a Cu cold-sprayed coating on an AA6061 aluminum substrate. This approach leverages the severe plastic deformation and high strain-rate environment inherent to friction stir processing to drive localized interdiffusion and solid-state reactions between the Cu coating and the Al alloy substrate. The processed surface exhibits a significant increase in hardness (≈ 250 HV), compared to both the AA6061 substrate (≈ 100 HV) and the as-deposited Cu coating (≈ 132 HV); these measured hardness values represent an increase of 1.8-times and 2.4-times relative to the Cu CS coating and AA6061 substrate, respectively. This hardness enhancement is attributed to the uniform distribution of fine-grained Al 2 Cu reinforcement within an Al(Cu) matrix, as confirmed by transmission electron microscopy and atom probe tomography. Unlike conventional precipitation hardening, here, discrete Al 2 Cu grains are directly formed and dispersed among Al grains, resulting in a hetero-grained microstructure that transitions into a single-phase matrix below the processed zone. Our results demonstrate the potential of integrating solid-state deposition with high-speed mechanical mixing to generate unique, non-equilibrium microstructures that bypass equilibrium melting constraints and exceed the performance of conventional thermomechanical processing routes. [ABSTRACT FROM AUTHOR]
ISSN:10474838
DOI:10.1007/s11837-025-07741-0