Bibliographic Details
| Title: |
A novel 0D germanium-based organic–inorganic hybrid material (C12H28N)GeCl3 showing reversible phase transition, dielectric anomaly and SHG response. |
| Authors: |
Zhou, Jie1 (AUTHOR), Tong, Binyi1 (AUTHOR), Zhong, Zhirong1 (AUTHOR), Duan, An1 (AUTHOR), Ai, Yong1 (AUTHOR), Zhou, Lin1 (AUTHOR), Wei, Zhenhong1 (AUTHOR), Cai, Hu1,2 (AUTHOR) |
| Source: |
Dalton Transactions: An International Journal of Inorganic Chemistry. 5/26/2026, Vol. 55 Issue 20, p7821-7825. 5p. |
| Subjects: |
Reversible phase transitions, Second harmonic generation, Dielectric properties, Photodetectors, Hybrid materials, Dielectric devices, Optical switches |
| Abstract: |
A novel zero-dimensional (0D) germanium-based organic–inorganic hybrid material, (C12H28N)GeCl3, was synthesized via a simple solution method. In the low-temperature phase, this compound crystallizes in the noncentrosymmetric space group (P63). The material undergoes a first-order reversible phase transition at 357 K/321 K and exhibits thermally induced reversible "on–off" SHG switching characteristics along with switchable dielectric behavior, as well as a direct band gap of 2.76 eV. This provides a new approach for the development of nonlinear optical switches, dielectric switching devices, and ultraviolet photodetectors. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
