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A novel 0D germanium-based organic–inorganic hybrid material (C12H28N)GeCl3 showing reversible phase transition, dielectric anomaly and SHG response.

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Title: A novel 0D germanium-based organic–inorganic hybrid material (C12H28N)GeCl3 showing reversible phase transition, dielectric anomaly and SHG response.
Authors: Zhou, Jie1 (AUTHOR), Tong, Binyi1 (AUTHOR), Zhong, Zhirong1 (AUTHOR), Duan, An1 (AUTHOR), Ai, Yong1 (AUTHOR), Zhou, Lin1 (AUTHOR), Wei, Zhenhong1 (AUTHOR), Cai, Hu1,2 (AUTHOR)
Source: Dalton Transactions: An International Journal of Inorganic Chemistry. 5/26/2026, Vol. 55 Issue 20, p7821-7825. 5p.
Subjects: Reversible phase transitions, Second harmonic generation, Dielectric properties, Photodetectors, Hybrid materials, Dielectric devices, Optical switches
Abstract: A novel zero-dimensional (0D) germanium-based organic–inorganic hybrid material, (C12H28N)GeCl3, was synthesized via a simple solution method. In the low-temperature phase, this compound crystallizes in the noncentrosymmetric space group (P63). The material undergoes a first-order reversible phase transition at 357 K/321 K and exhibits thermally induced reversible "on–off" SHG switching characteristics along with switchable dielectric behavior, as well as a direct band gap of 2.76 eV. This provides a new approach for the development of nonlinear optical switches, dielectric switching devices, and ultraviolet photodetectors. [ABSTRACT FROM AUTHOR]
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
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AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
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  Label: Title
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  Data: A novel 0D germanium-based organic–inorganic hybrid material (C<subscript>12</subscript>H<subscript>28</subscript>N)GeCl<subscript>3</subscript> showing reversible phase transition, dielectric anomaly and SHG response.
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  Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. 5/26/2026, Vol. 55 Issue 20, p7821-7825. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Reversible+phase+transitions%22">Reversible phase transitions</searchLink><br /><searchLink fieldCode="DE" term="%22Second+harmonic+generation%22">Second harmonic generation</searchLink><br /><searchLink fieldCode="DE" term="%22Dielectric+properties%22">Dielectric properties</searchLink><br /><searchLink fieldCode="DE" term="%22Photodetectors%22">Photodetectors</searchLink><br /><searchLink fieldCode="DE" term="%22Hybrid+materials%22">Hybrid materials</searchLink><br /><searchLink fieldCode="DE" term="%22Dielectric+devices%22">Dielectric devices</searchLink><br /><searchLink fieldCode="DE" term="%22Optical+switches%22">Optical switches</searchLink>
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  Label: Abstract
  Group: Ab
  Data: A novel zero-dimensional (0D) germanium-based organic–inorganic hybrid material, (C12H28N)GeCl3, was synthesized via a simple solution method. In the low-temperature phase, this compound crystallizes in the noncentrosymmetric space group (P63). The material undergoes a first-order reversible phase transition at 357 K/321 K and exhibits thermally induced reversible "on–off" SHG switching characteristics along with switchable dielectric behavior, as well as a direct band gap of 2.76 eV. This provides a new approach for the development of nonlinear optical switches, dielectric switching devices, and ultraviolet photodetectors. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1039/d6dt00723f
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        Text: English
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        Type: general
      – SubjectFull: Second harmonic generation
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      – SubjectFull: Dielectric properties
        Type: general
      – SubjectFull: Photodetectors
        Type: general
      – SubjectFull: Hybrid materials
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      – SubjectFull: Dielectric devices
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      – SubjectFull: Optical switches
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              M: 05
              Text: 5/26/2026
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              Y: 2026
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