View in EDS

Determination and correction of systematic errors in surface-enhanced LIBS.

Saved in:
Bibliographic Details
Title: Determination and correction of systematic errors in surface-enhanced LIBS.
Authors: Li, Dongdong1 (AUTHOR), Liu, Kelong1 (AUTHOR), Sun, Zhongfa1 (AUTHOR), Yang, Xinyan1 (AUTHOR) xinyanyang@ahnu.edu.cn, Zheng, Xianfeng1 (AUTHOR)
Source: JAAS (Journal of Analytical Atomic Spectrometry). Jun2026, Vol. 41 Issue 6, p2068-2073. 6p.
Subjects: Calibration, Matrix effect, Statistical bias, Trace element analysis, Statistical accuracy, Sewage, Laser-induced breakdown spectroscopy
Abstract: Surface-enhanced laser-induced breakdown spectroscopy (SENLIBS) enhances the detection sensitivity for liquid analysis by transforming the sample into a solid-phase analyte layer on a substrate surface. However, this process introduces solid substrate-induced matrix effects, which manifest as proportional and constant systematic errors and ultimately compromise quantitative accuracy. This study employs ANCOVA to identify systematic errors by comparing the slopes of Basic Calibration (BC), Youden Calibration (YC), and Standard Addition Calibration (SAC). To address these errors, a novel calibration strategy that combines matrix dilution with Youden calibration is then proposed. The method was validated with Cr and Pb in water; it improved quantitative accuracy by up to 97.5% and 97.0%, respectively, across different standard addition systems. Recovery tests with real wastewater samples further confirmed its practicality, achieving a Pb recovery rate of 95.0%. The proposed hybrid correction framework provides a robust, model-based solution for enhancing the accuracy of SENLIBS in trace element analysis. [ABSTRACT FROM AUTHOR]
Copyright of JAAS (Journal of Analytical Atomic Spectrometry) is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 194455518
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Determination and correction of systematic errors in surface-enhanced LIBS.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Li%2C+Dongdong%22">Li, Dongdong</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Liu%2C+Kelong%22">Liu, Kelong</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sun%2C+Zhongfa%22">Sun, Zhongfa</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Yang%2C+Xinyan%22">Yang, Xinyan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<i> xinyanyang@ahnu.edu.cn</i><br /><searchLink fieldCode="AR" term="%22Zheng%2C+Xianfeng%22">Zheng, Xianfeng</searchLink><relatesTo>1</relatesTo> (AUTHOR)
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22JAAS+%28Journal+of+Analytical+Atomic+Spectrometry%29%22">JAAS (Journal of Analytical Atomic Spectrometry)</searchLink>. Jun2026, Vol. 41 Issue 6, p2068-2073. 6p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Calibration%22">Calibration</searchLink><br /><searchLink fieldCode="DE" term="%22Matrix+effect%22">Matrix effect</searchLink><br /><searchLink fieldCode="DE" term="%22Statistical+bias%22">Statistical bias</searchLink><br /><searchLink fieldCode="DE" term="%22Trace+element+analysis%22">Trace element analysis</searchLink><br /><searchLink fieldCode="DE" term="%22Statistical+accuracy%22">Statistical accuracy</searchLink><br /><searchLink fieldCode="DE" term="%22Sewage%22">Sewage</searchLink><br /><searchLink fieldCode="DE" term="%22Laser-induced+breakdown+spectroscopy%22">Laser-induced breakdown spectroscopy</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: Surface-enhanced laser-induced breakdown spectroscopy (SENLIBS) enhances the detection sensitivity for liquid analysis by transforming the sample into a solid-phase analyte layer on a substrate surface. However, this process introduces solid substrate-induced matrix effects, which manifest as proportional and constant systematic errors and ultimately compromise quantitative accuracy. This study employs ANCOVA to identify systematic errors by comparing the slopes of Basic Calibration (BC), Youden Calibration (YC), and Standard Addition Calibration (SAC). To address these errors, a novel calibration strategy that combines matrix dilution with Youden calibration is then proposed. The method was validated with Cr and Pb in water; it improved quantitative accuracy by up to 97.5% and 97.0%, respectively, across different standard addition systems. Recovery tests with real wastewater samples further confirmed its practicality, achieving a Pb recovery rate of 95.0%. The proposed hybrid correction framework provides a robust, model-based solution for enhancing the accuracy of SENLIBS in trace element analysis. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of JAAS (Journal of Analytical Atomic Spectrometry) is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=194455518
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1039/d6ja00005c
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 6
        StartPage: 2068
    Subjects:
      – SubjectFull: Calibration
        Type: general
      – SubjectFull: Matrix effect
        Type: general
      – SubjectFull: Statistical bias
        Type: general
      – SubjectFull: Trace element analysis
        Type: general
      – SubjectFull: Statistical accuracy
        Type: general
      – SubjectFull: Sewage
        Type: general
      – SubjectFull: Laser-induced breakdown spectroscopy
        Type: general
    Titles:
      – TitleFull: Determination and correction of systematic errors in surface-enhanced LIBS.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Li, Dongdong
      – PersonEntity:
          Name:
            NameFull: Liu, Kelong
      – PersonEntity:
          Name:
            NameFull: Sun, Zhongfa
      – PersonEntity:
          Name:
            NameFull: Yang, Xinyan
      – PersonEntity:
          Name:
            NameFull: Zheng, Xianfeng
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 01
              M: 06
              Text: Jun2026
              Type: published
              Y: 2026
          Identifiers:
            – Type: issn-print
              Value: 02679477
          Numbering:
            – Type: volume
              Value: 41
            – Type: issue
              Value: 6
          Titles:
            – TitleFull: JAAS (Journal of Analytical Atomic Spectrometry)
              Type: main
ResultId 1