High-Electron-Mobility and Ultrawide-Bandgap β-(AlxInyGa1−x−y)2O3 Lattice-Matched to β-Ga2O3.

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Title: High-Electron-Mobility and Ultrawide-Bandgap β-(AlxInyGa1−x−y)2O3 Lattice-Matched to β-Ga2O3.
Authors: Zha, Xian-Hu1 (AUTHOR), Li, Shuang2 (AUTHOR), Chen, Jiaxiang1 (AUTHOR), Yang, Maojin1 (AUTHOR), Jiao, Teng1 (AUTHOR), Liu, Yan1 (AUTHOR), Fan, Weijun3 (AUTHOR), Wan, Yu-Xi1 (AUTHOR), Zhang, Dao Hua1 (AUTHOR) zhangdaohua@phlab.com.cn
Source: Journal of Electronic Materials. Jul2026, Vol. 55 Issue 7, p6167-6177. 11p.
Subjects: Electron mobility, Wide gap semiconductors, Metal oxide semiconductors, Power electronics, Ab-initio calculations
Abstract: Maintaining a wide bandgap while enhancing electron mobility is crucial for advancing the performance of β-Ga2O3-based power devices. Herein, the structural and electronic properties of quaternary β-(AlxInyGa1−x−y)2O3 (0 ≤ x ≤ 0.09375; 0 ≤ y ≤ 0.09375; x−y ≤ −0.03125) are studied via first-principles calculations. Given its predicted minimal lattice mismatch of less than 1.09% with β-Ga2O3, β-(AlxInyGa1−x−y)2O3 can be epitaxially grown on β-Ga2O3 substrates. The bandgaps of β-(AlxInyGa1−x−y)2O3 are calculated and fitted to the function of gap = 1.82x − 1.80y − 8.32x⋅y + 4.81, with all values determined to exceed 4.68 eV. Notably, β-(AlxInyGa1−x−y)2O3 exhibits high and anisotropic electron mobility. At an electron concentration of 1016 cm−3, the average electron mobility of β-(Al0.0625In0.09375Ga0.84375)2O3 reaches 501 cm2V−1 s−1, which is 3.98 times that of β-Ga2O3. Specifically, the electron mobility along the b-axis of β-(AlxInyGa1−x−y)2O3 is consistently higher, and room-temperature mobility of 1153 cm2V−1 s−1 is achieved for a β-(Al0.0625In0.09375Ga0.84375)2O3 configuration. The high electron mobility is attributed to the delocalized nature of the In 5s orbital, which makes a greater contribution to the conduction band minimum of β-(AlxInyGa1−x−y)2O3. The anisotropy of electron mobility in β-(AlxInyGa1−x−y)2O3 strongly depends on the distribution of In atoms, and the higher mobility values along the b-axis are due to the more compact atomic arrangement in this direction. Our results suggest that β-(AlxInyGa1−x−y)2O3 holds significant potential for high-power device applications. [ABSTRACT FROM AUTHOR]
Copyright of Journal of Electronic Materials is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: <searchLink fieldCode="DE" term="%22Electron+mobility%22">Electron mobility</searchLink><br /><searchLink fieldCode="DE" term="%22Wide+gap+semiconductors%22">Wide gap semiconductors</searchLink><br /><searchLink fieldCode="DE" term="%22Metal+oxide+semiconductors%22">Metal oxide semiconductors</searchLink><br /><searchLink fieldCode="DE" term="%22Power+electronics%22">Power electronics</searchLink><br /><searchLink fieldCode="DE" term="%22Ab-initio+calculations%22">Ab-initio calculations</searchLink>
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  Data: Maintaining a wide bandgap while enhancing electron mobility is crucial for advancing the performance of β-Ga2O3-based power devices. Herein, the structural and electronic properties of quaternary β-(AlxInyGa1−x−y)2O3 (0 ≤ x ≤ 0.09375; 0 ≤ y ≤ 0.09375; x−y ≤ −0.03125) are studied via first-principles calculations. Given its predicted minimal lattice mismatch of less than 1.09% with β-Ga2O3, β-(AlxInyGa1−x−y)2O3 can be epitaxially grown on β-Ga2O3 substrates. The bandgaps of β-(AlxInyGa1−x−y)2O3 are calculated and fitted to the function of gap = 1.82x − 1.80y − 8.32x⋅y + 4.81, with all values determined to exceed 4.68 eV. Notably, β-(AlxInyGa1−x−y)2O3 exhibits high and anisotropic electron mobility. At an electron concentration of 1016 cm−3, the average electron mobility of β-(Al0.0625In0.09375Ga0.84375)2O3 reaches 501 cm2V−1 s−1, which is 3.98 times that of β-Ga2O3. Specifically, the electron mobility along the b-axis of β-(AlxInyGa1−x−y)2O3 is consistently higher, and room-temperature mobility of 1153 cm2V−1 s−1 is achieved for a β-(Al0.0625In0.09375Ga0.84375)2O3 configuration. The high electron mobility is attributed to the delocalized nature of the In 5s orbital, which makes a greater contribution to the conduction band minimum of β-(AlxInyGa1−x−y)2O3. The anisotropy of electron mobility in β-(AlxInyGa1−x−y)2O3 strongly depends on the distribution of In atoms, and the higher mobility values along the b-axis are due to the more compact atomic arrangement in this direction. Our results suggest that β-(AlxInyGa1−x−y)2O3 holds significant potential for high-power device applications. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Journal of Electronic Materials is the property of Springer Nature and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1007/s11664-026-12904-z
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      – Code: eng
        Text: English
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        PageCount: 11
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      – SubjectFull: Electron mobility
        Type: general
      – SubjectFull: Wide gap semiconductors
        Type: general
      – SubjectFull: Metal oxide semiconductors
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      – SubjectFull: Power electronics
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      – SubjectFull: Ab-initio calculations
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      – TitleFull: High-Electron-Mobility and Ultrawide-Bandgap β-(AlxInyGa1−x−y)2O3 Lattice-Matched to β-Ga2O3.
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              Text: Jul2026
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