Influence of Rhenium Content on Vacancy-Type Defect Distribution in Mo–Re Alloys Under Room-Temperature Irradiation.

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Title: Influence of Rhenium Content on Vacancy-Type Defect Distribution in Mo–Re Alloys Under Room-Temperature Irradiation.
Authors: Liu, Yongli1 (AUTHOR), Yang, Qigui2 (AUTHOR), Zhou, Yunpeng2,3 (AUTHOR), Fu, Tong1 (AUTHOR), Chai, Linjiang2,3 (AUTHOR), Cao, Xingzhong2,3 (AUTHOR)
Source: Materials (1996-1944). Jun2026, Vol. 19 Issue 12, p2632. 22p.
Subjects: Molybdenum alloys, Point defects, Irradiation, Nuclear reactor materials, Ion bombardment
Abstract: Mo–Re alloys serve as critical structural components for high-temperature nuclear reactors, and their irradiation degradation is closely related to the evolution of vacancy-type defects. In this study, heavy-ion and He-ion irradiations were performed under RT to introduce an average displacement damage of 3.5 dpa within the 1 μm-thick surface layer of Mo–Re alloys with Re content up to 47 wt.%. PALS, SPB-DBS and CDB techniques were employed to characterize the size, concentration, depth distribution and local chemical environment of irradiation-induced vacancy-type defects. The results demonstrate that the longer lifetime component of irradiated Mo–Re alloys ranged from 262 to 280 ps, corresponding to medium-sized vacancy clusters. The S parameter of all specimens increased significantly from approximately 0.42 to 0.50, with negligible differences (<0.01) among various Mo–Re alloys. No distinct characteristic peak of Re was observed near 17 × 10−3 m0c at the vacancy sites, which was inconsistent with simulation predictions. Mo–Re alloys exhibit similar vacancy-type defect features to pure Mo, implying weak interactions between Re solute atoms and vacancy-type defects under RT irradiation. [ABSTRACT FROM AUTHOR]
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Abstract:Mo–Re alloys serve as critical structural components for high-temperature nuclear reactors, and their irradiation degradation is closely related to the evolution of vacancy-type defects. In this study, heavy-ion and He-ion irradiations were performed under RT to introduce an average displacement damage of 3.5 dpa within the 1 μm-thick surface layer of Mo–Re alloys with Re content up to 47 wt.%. PALS, SPB-DBS and CDB techniques were employed to characterize the size, concentration, depth distribution and local chemical environment of irradiation-induced vacancy-type defects. The results demonstrate that the longer lifetime component of irradiated Mo–Re alloys ranged from 262 to 280 ps, corresponding to medium-sized vacancy clusters. The S parameter of all specimens increased significantly from approximately 0.42 to 0.50, with negligible differences (<0.01) among various Mo–Re alloys. No distinct characteristic peak of Re was observed near 17 × 10−3 m0c at the vacancy sites, which was inconsistent with simulation predictions. Mo–Re alloys exhibit similar vacancy-type defect features to pure Mo, implying weak interactions between Re solute atoms and vacancy-type defects under RT irradiation. [ABSTRACT FROM AUTHOR]
ISSN:19961944
DOI:10.3390/ma19122632