Bibliographic Details
| Title: |
Metal dilution enabled quantum coherence in a planar Ni(III) dmit complex. |
| Authors: |
Tominaga, Ryuto1 (AUTHOR), Saha, Sayan1 (AUTHOR), Miyake, Kanta1 (AUTHOR), Zenno, Hikaru1 (AUTHOR), Asada, Mizue2 (AUTHOR), Nakamura, Toshikazu2 (AUTHOR), Sekine, Yoshihiro1,3 (AUTHOR), Hayami, Shinya1,3,4 (AUTHOR) hayami@kumamoto-u.ac.jp |
| Source: |
Dalton Transactions: An International Journal of Inorganic Chemistry. 6/30/2026, Vol. 55 Issue 25, p9563-9567. 5p. |
| Subjects: |
Quantum coherence, Rabi oscillations, Coordination compounds, Single molecule magnets, Spin-lattice relaxation, Electron spin |
| Abstract: |
Magnetically diluted (TBA)[NixAu1−x(dmit)2] samples were prepared by incorporating Ni(III) centres into an isostructural diamagnetic Au(dmit)2 lattice to reduce intermolecular antiferromagnetic interactions. The diluted complex exhibits slow relaxation, long spin–lattice relaxation and coherence times at 4 K, and clear Rabi oscillations, indicating that planar Ni(III)-dmit complexes can support molecular-spin-qubit behaviour. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
