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Metal dilution enabled quantum coherence in a planar Ni(III) dmit complex.

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Title: Metal dilution enabled quantum coherence in a planar Ni(III) dmit complex.
Authors: Tominaga, Ryuto1 (AUTHOR), Saha, Sayan1 (AUTHOR), Miyake, Kanta1 (AUTHOR), Zenno, Hikaru1 (AUTHOR), Asada, Mizue2 (AUTHOR), Nakamura, Toshikazu2 (AUTHOR), Sekine, Yoshihiro1,3 (AUTHOR), Hayami, Shinya1,3,4 (AUTHOR) hayami@kumamoto-u.ac.jp
Source: Dalton Transactions: An International Journal of Inorganic Chemistry. 6/30/2026, Vol. 55 Issue 25, p9563-9567. 5p.
Subjects: Quantum coherence, Rabi oscillations, Coordination compounds, Single molecule magnets, Spin-lattice relaxation, Electron spin
Abstract: Magnetically diluted (TBA)[NixAu1−x(dmit)2] samples were prepared by incorporating Ni(III) centres into an isostructural diamagnetic Au(dmit)2 lattice to reduce intermolecular antiferromagnetic interactions. The diluted complex exhibits slow relaxation, long spin–lattice relaxation and coherence times at 4 K, and clear Rabi oscillations, indicating that planar Ni(III)-dmit complexes can support molecular-spin-qubit behaviour. [ABSTRACT FROM AUTHOR]
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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Header DbId: egs
DbLabel: Engineering Source
An: 194992347
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
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  Data: Metal dilution enabled quantum coherence in a planar Ni(III) dmit complex.
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  Data: <searchLink fieldCode="AR" term="%22Tominaga%2C+Ryuto%22">Tominaga, Ryuto</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Saha%2C+Sayan%22">Saha, Sayan</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Miyake%2C+Kanta%22">Miyake, Kanta</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Zenno%2C+Hikaru%22">Zenno, Hikaru</searchLink><relatesTo>1</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Asada%2C+Mizue%22">Asada, Mizue</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Nakamura%2C+Toshikazu%22">Nakamura, Toshikazu</searchLink><relatesTo>2</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Sekine%2C+Yoshihiro%22">Sekine, Yoshihiro</searchLink><relatesTo>1,3</relatesTo> (AUTHOR)<br /><searchLink fieldCode="AR" term="%22Hayami%2C+Shinya%22">Hayami, Shinya</searchLink><relatesTo>1,3,4</relatesTo> (AUTHOR)<i> hayami@kumamoto-u.ac.jp</i>
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  Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. 6/30/2026, Vol. 55 Issue 25, p9563-9567. 5p.
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  Data: <searchLink fieldCode="DE" term="%22Quantum+coherence%22">Quantum coherence</searchLink><br /><searchLink fieldCode="DE" term="%22Rabi+oscillations%22">Rabi oscillations</searchLink><br /><searchLink fieldCode="DE" term="%22Coordination+compounds%22">Coordination compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Single+molecule+magnets%22">Single molecule magnets</searchLink><br /><searchLink fieldCode="DE" term="%22Spin-lattice+relaxation%22">Spin-lattice relaxation</searchLink><br /><searchLink fieldCode="DE" term="%22Electron+spin%22">Electron spin</searchLink>
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  Label: Abstract
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  Data: Magnetically diluted (TBA)[NixAu1−x(dmit)2] samples were prepared by incorporating Ni(III) centres into an isostructural diamagnetic Au(dmit)2 lattice to reduce intermolecular antiferromagnetic interactions. The diluted complex exhibits slow relaxation, long spin–lattice relaxation and coherence times at 4 K, and clear Rabi oscillations, indicating that planar Ni(III)-dmit complexes can support molecular-spin-qubit behaviour. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
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  Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1039/d6dt00538a
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      – SubjectFull: Coordination compounds
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      – SubjectFull: Single molecule magnets
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      – SubjectFull: Spin-lattice relaxation
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      – SubjectFull: Electron spin
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              M: 06
              Text: 6/30/2026
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