Bibliographic Details
| Title: |
Transformation of an η1-coordinated phosphaalkyne into a bridging phosphinidene ligand |
| Authors: |
Andrews, Christopher D.1, Burrows, Andrew D.1, Green, Michael1,2, Lynam, Jason M.1,3 jml12@york.ac.uk, Mahon, Mary F.1 |
| Source: |
Journal of Organometallic Chemistry. Jun2006, Vol. 691 Issue 13, p2859-2862. 4p. |
| Subjects: |
Alkynes, X-ray crystallography, Ligands (Chemistry), Acetone |
| Abstract: |
Abstract: The tripalladium cluster [Pd3(μ3-CO)(μ-dppm)3](PF6)2 (1) reacts with two equivalents of t BuCP to give [Pd3(μ-dppm)3(η1-PCBu t )2](PF6)2 (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd3(μ-dppm)3(η1:μ3-PCH2Bu t )(OCMe2)](PF6)2 (3). Compound 3 has been characterized by X-ray crystallography. [Copyright &y& Elsevier] |
|
Copyright of Journal of Organometallic Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| Database: |
Engineering Source |
