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Transformation of an η1-coordinated phosphaalkyne into a bridging phosphinidene ligand

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Title: Transformation of an η1-coordinated phosphaalkyne into a bridging phosphinidene ligand
Authors: Andrews, Christopher D.1, Burrows, Andrew D.1, Green, Michael1,2, Lynam, Jason M.1,3 jml12@york.ac.uk, Mahon, Mary F.1
Source: Journal of Organometallic Chemistry. Jun2006, Vol. 691 Issue 13, p2859-2862. 4p.
Subjects: Alkynes, X-ray crystallography, Ligands (Chemistry), Acetone
Abstract: Abstract: The tripalladium cluster [Pd3(μ3-CO)(μ-dppm)3](PF6)2 (1) reacts with two equivalents of t BuCP to give [Pd3(μ-dppm)3(η1-PCBu t )2](PF6)2 (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd3(μ-dppm)3(η1:μ3-PCH2Bu t )(OCMe2)](PF6)2 (3). Compound 3 has been characterized by X-ray crystallography. [Copyright &y& Elsevier]
Copyright of Journal of Organometallic Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
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DbLabel: Engineering Source
An: 20876120
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PubType: Academic Journal
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  Data: Transformation of an η<superscript>1</superscript>-coordinated phosphaalkyne into a bridging phosphinidene ligand
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  Data: <searchLink fieldCode="AR" term="%22Andrews%2C+Christopher+D%2E%22">Andrews, Christopher D.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Burrows%2C+Andrew+D%2E%22">Burrows, Andrew D.</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Green%2C+Michael%22">Green, Michael</searchLink><relatesTo>1,2</relatesTo><br /><searchLink fieldCode="AR" term="%22Lynam%2C+Jason+M%2E%22">Lynam, Jason M.</searchLink><relatesTo>1,3</relatesTo><i> jml12@york.ac.uk</i><br /><searchLink fieldCode="AR" term="%22Mahon%2C+Mary+F%2E%22">Mahon, Mary F.</searchLink><relatesTo>1</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+Organometallic+Chemistry%22">Journal of Organometallic Chemistry</searchLink>. Jun2006, Vol. 691 Issue 13, p2859-2862. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Alkynes%22">Alkynes</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+crystallography%22">X-ray crystallography</searchLink><br /><searchLink fieldCode="DE" term="%22Ligands+%28Chemistry%29%22">Ligands (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22Acetone%22">Acetone</searchLink>
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  Data: Abstract: The tripalladium cluster [Pd3(μ3-CO)(μ-dppm)3](PF6)2 (1) reacts with two equivalents of t BuCP to give [Pd3(μ-dppm)3(η1-PCBu t )2](PF6)2 (2). Prolonged storage of acetone solutions of 2 only resulted in the isolation of [Pd3(μ-dppm)3(η1:μ3-PCH2Bu t )(OCMe2)](PF6)2 (3). Compound 3 has been characterized by X-ray crystallography. [Copyright &y& Elsevier]
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  Data: <i>Copyright of Journal of Organometallic Chemistry is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.jorganchem.2006.03.014
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              Text: Jun2006
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