Bibliographic Details
| Title: |
Anion–ligand interaction in binuclear cyclic dimer complex of a tribenzo-S2O2 macrocycle with silver(I) picrate |
| Authors: |
Seo, Joobeom1, Song, Mi Ryoung1, Sultana, Kaniz Fatima1, Kim, Hyun Jee1, Kim, Jineun1, Lee, Shim Sung sslee@gsnu.ac.kr |
| Source: |
Journal of Molecular Structure. Feb2007, Vol. 827 Issue 1-3, p201-205. 5p. |
| Subjects: |
Macrocyclic compounds, Anions, X-ray diffraction, Nuclear magnetic resonance |
| Abstract: |
Abstract: From the reaction of tribenzo-S2O2 macrocyclic ligand (L 1) and silver picrate (AgPic), a unique binuclear complex [Ag2(L 1)2(Pic)2] (1) has been obtained. The species 1 has been characterised by single-crystal X-ray diffraction analysis providing a definitive proof of its cyclic dimer structure as well as the anion–ligand π–π stacking interactions between L 1 and Pic−. The result of a comparative NMR experiment suggests that the solid structure of 1 is also retained in solution. [Copyright &y& Elsevier] |
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| Database: |
Engineering Source |
