Bibliographic Details
| Title: |
Unexpected oxidation of a diphosphine by bis(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2]. |
| Authors: |
Harding, David J.1 hdavid@wu.ac.th, Harding, Phimphaka1, Thurakitseree, Theerapol2, Adams, Harry3 |
| Source: |
Acta Crystallographica: Section C (Wiley-Blackwell). Apr2007, Vol. 63 Issue 4, pm163-m165. 1p. 3 Diagrams, 1 Chart. |
| Subjects: |
Phosphine, Oxidation, Organocobalt compounds, Chemical reactions, Polymers, Coordination compounds |
| Abstract: |
The reaction of bis(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2], with bis(diphenylphosphino)ethane (dppe) affords the coordination polymer catena-poly[[bis(1,3-diphenylpropane-1,3-dionato-κ2 O, O′)cobalt(II)]-μ-ethylenebis(diphenylphosphine oxide)-κ2 O: O′], trans-[Co(C15H11O2)2(C26H24O2P2)] n, as a result of oxidation of the diphosphine. The Co atom is octahedral, with a CoO6 coordination sphere, and the chelating dbm ligands adopt a trans configuration. The Co atom also lies on a centre of inversion, with a further symmetry centre bisecting the bridging ethylenebis(diphenylphosphine oxide) ligand. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
