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Unexpected oxidation of a diphos­phine by bis­(1,3-diphenylpropane-1,3-dionato)­cobalt(II), [Co(dbm)2].

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Title: Unexpected oxidation of a diphos­phine by bis­(1,3-diphenylpropane-1,3-dionato)­cobalt(II), [Co(dbm)2].
Authors: Harding, David J.1 hdavid@wu.ac.th, Harding, Phimphaka1, Thurakitseree, Theerapol2, Adams, Harry3
Source: Acta Crystallographica: Section C (Wiley-Blackwell). Apr2007, Vol. 63 Issue 4, pm163-m165. 1p. 3 Diagrams, 1 Chart.
Subjects: Phosphine, Oxidation, Organocobalt compounds, Chemical reactions, Polymers, Coordination compounds
Abstract: The reaction of bis­(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2], with bis­(diphenyl­phosphino)ethane (dppe) affords the coordination polymer catena-poly[[bis­(1,3-diphenyl­propane-1,3-dionato-κ2 O, O′)cobalt(II)]-μ-ethyl­enebis(diphenyl­phosphine oxide)-κ2 O: O′], trans-[Co(C15H11O2)2(C26H24O2P2)] n, as a result of oxidation of the diphos­phine. The Co atom is octa­hedral, with a CoO6 coordination sphere, and the chelating dbm ligands adopt a trans configuration. The Co atom also lies on a centre of inversion, with a further symmetry centre bis­ecting the bridging ethyl­enebis(diphenyl­phosphine oxide) ligand. [ABSTRACT FROM AUTHOR]
Copyright of Acta Crystallographica: Section C (Wiley-Blackwell) is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Unexpected oxidation of a diphos­phine by bis­(1,3-diphenylpropane-1,3-dionato)­cobalt(II), [Co(dbm)<subscript>2</subscript>].
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  Data: <searchLink fieldCode="AR" term="%22Harding%2C+David+J%2E%22">Harding, David J.</searchLink><relatesTo>1</relatesTo><i> hdavid@wu.ac.th</i><br /><searchLink fieldCode="AR" term="%22Harding%2C+Phimphaka%22">Harding, Phimphaka</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Thurakitseree%2C+Theerapol%22">Thurakitseree, Theerapol</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Adams%2C+Harry%22">Adams, Harry</searchLink><relatesTo>3</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Acta+Crystallographica%3A+Section+C+%28Wiley-Blackwell%29%22">Acta Crystallographica: Section C (Wiley-Blackwell)</searchLink>. Apr2007, Vol. 63 Issue 4, pm163-m165. 1p. 3 Diagrams, 1 Chart.
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  Data: <searchLink fieldCode="DE" term="%22Phosphine%22">Phosphine</searchLink><br /><searchLink fieldCode="DE" term="%22Oxidation%22">Oxidation</searchLink><br /><searchLink fieldCode="DE" term="%22Organocobalt+compounds%22">Organocobalt compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Chemical+reactions%22">Chemical reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Polymers%22">Polymers</searchLink><br /><searchLink fieldCode="DE" term="%22Coordination+compounds%22">Coordination compounds</searchLink>
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  Data: The reaction of bis­(1,3-diphenylpropane-1,3-dionato)cobalt(II), [Co(dbm)2], with bis­(diphenyl­phosphino)ethane (dppe) affords the coordination polymer catena-poly[[bis­(1,3-diphenyl­propane-1,3-dionato-κ2 O, O′)cobalt(II)]-μ-ethyl­enebis(diphenyl­phosphine oxide)-κ2 O: O′], trans-[Co(C15H11O2)2(C26H24O2P2)] n, as a result of oxidation of the diphos­phine. The Co atom is octa­hedral, with a CoO6 coordination sphere, and the chelating dbm ligands adopt a trans configuration. The Co atom also lies on a centre of inversion, with a further symmetry centre bis­ecting the bridging ethyl­enebis(diphenyl­phosphine oxide) ligand. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
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  Data: <i>Copyright of Acta Crystallographica: Section C (Wiley-Blackwell) is the property of Wiley-Blackwell and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – Type: doi
        Value: 10.1107/S010827010700933X
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      – Code: eng
        Text: English
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      – SubjectFull: Phosphine
        Type: general
      – SubjectFull: Oxidation
        Type: general
      – SubjectFull: Organocobalt compounds
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      – SubjectFull: Chemical reactions
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      – SubjectFull: Polymers
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      – SubjectFull: Coordination compounds
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      – TitleFull: Unexpected oxidation of a diphos­phine by bis­(1,3-diphenylpropane-1,3-dionato)­cobalt(II), [Co(dbm)2].
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              Text: Apr2007
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              Y: 2007
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