Branching, aggregation, and phase separation during the gelation of tetraethoxysilane

Saved in:
Bibliographic Details
Title: Branching, aggregation, and phase separation during the gelation of tetraethoxysilane
Authors: Gommes, Cédric J.1 cedric.gommes@ulg.ac.be, Goderis, Bart2, Pirard, Jean-Paul1, Blacher, Silvia1
Source: Journal of Non-Crystalline Solids. Jul2007, Vol. 353 Issue 24/25, p2495-2499. 5p.
Subjects: X-ray scattering, Colloids, Silicon compounds, Polymerization
Abstract: Abstract: Time-resolved small-angle X-ray scattering is used to follow in situ the structuring of silica sols and gels in various chemical conditions. The acid-catalyzed and base-catalyzed polymerizations of TEOS, as well as the copolymerization of TEOS with organically modified trialkoxysilanes, are followed. The analysis points to the diversity of the mechanisms that govern the structuring of the reacting solutions, and most notably to the important role of physical forces. [Copyright &y& Elsevier]
Copyright of Journal of Non-Crystalline Solids is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
Description
Abstract:Abstract: Time-resolved small-angle X-ray scattering is used to follow in situ the structuring of silica sols and gels in various chemical conditions. The acid-catalyzed and base-catalyzed polymerizations of TEOS, as well as the copolymerization of TEOS with organically modified trialkoxysilanes, are followed. The analysis points to the diversity of the mechanisms that govern the structuring of the reacting solutions, and most notably to the important role of physical forces. [Copyright &y& Elsevier]
ISSN:00223093
DOI:10.1016/j.jnoncrysol.2007.04.009