Bibliographic Details
| Title: |
Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]: A novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ionsElectronic supplementary information (ESI) available: Tables of anisotropic thermal parameters, and bond distances and angles for 1. Polyhedral representation and schematic depiction of crystal packing of 1, IR spectrum, 1H NMR and 13C NMR, powder X-ray diffraction patterns, fluorescence emission spectra and excitation spectra. See DOI: 10.1039/b708799c |
| Authors: |
Geng-Geng Luo1, Li-Rong Lin2, Rong-Bin Huang3, Lan-Sun Zheng4,5 |
| Source: |
Dalton Transactions: An International Journal of Inorganic Chemistry. Aug2007, Vol. 2007 Issue 35, p3868-3870. 3p. |
| Subjects: |
Silver ions, Silver compounds, Zinc, X-ray crystallography |
| Abstract: |
[Ag(UO2)3 (OAc)9][Zn(H2O)4(CH3CH2OH)2] (1, OAc = CH3COO−) crystallized from an ethanol solution and its structure was determined by IR spectroscopy, elemental analysis, 1H NMR, 13C NMR and X-ray crystallography; it is composed of [Zn(H2O)4(CH3CH2OH)2]2+ cations and [Ag(UO2)3(OAc)9]2− anions in which triuranyl [(UO2)(OAc)3]3 clusters are linked by the Ag ion. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
