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Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]: A novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ionsElectronic supplementary information (ESI) available: Tables of anisotropic thermal parameters, and bond distances and angles for 1. Polyhedral representation and schematic depiction of crystal packing of 1, IR spectrum, 1H NMR and 13C NMR, powder X-ray diffraction patterns, fluorescence emission spectra and excitation spectra. See DOI: 10.1039/b708799c

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Title: Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]: A novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ionsElectronic supplementary information (ESI) available: Tables of anisotropic thermal parameters, and bond distances and angles for 1. Polyhedral representation and schematic depiction of crystal packing of 1, IR spectrum, 1H NMR and 13C NMR, powder X-ray diffraction patterns, fluorescence emission spectra and excitation spectra. See DOI: 10.1039/b708799c
Authors: Geng-Geng Luo1, Li-Rong Lin2, Rong-Bin Huang3, Lan-Sun Zheng4,5
Source: Dalton Transactions: An International Journal of Inorganic Chemistry. Aug2007, Vol. 2007 Issue 35, p3868-3870. 3p.
Subjects: Silver ions, Silver compounds, Zinc, X-ray crystallography
Abstract: [Ag(UO2)3 (OAc)9][Zn(H2O)4(CH3CH2OH)2] (1, OAc = CH3COO−) crystallized from an ethanol solution and its structure was determined by IR spectroscopy, elemental analysis, 1H NMR, 13C NMR and X-ray crystallography; it is composed of [Zn(H2O)4(CH3CH2OH)2]2+ cations and [Ag(UO2)3(OAc)9]2− anions in which triuranyl [(UO2)(OAc)3]3 clusters are linked by the Ag ion. [ABSTRACT FROM AUTHOR]
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]: A novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ionsElectronic supplementary information (ESI) available: Tables of anisotropic thermal parameters, and bond distances and angles for 1. Polyhedral representation and schematic depiction of crystal packing of 1, IR spectrum, 1H NMR and 13C NMR, powder X-ray diffraction patterns, fluorescence emission spectra and excitation spectra. See DOI: 10.1039/b708799c
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  Data: <searchLink fieldCode="AR" term="%22Geng-Geng+Luo%22">Geng-Geng Luo</searchLink><relatesTo>1</relatesTo><br /><searchLink fieldCode="AR" term="%22Li-Rong+Lin%22">Li-Rong Lin</searchLink><relatesTo>2</relatesTo><br /><searchLink fieldCode="AR" term="%22Rong-Bin+Huang%22">Rong-Bin Huang</searchLink><relatesTo>3</relatesTo><br /><searchLink fieldCode="AR" term="%22Lan-Sun+Zheng%22">Lan-Sun Zheng</searchLink><relatesTo>4,5</relatesTo>
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  Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. Aug2007, Vol. 2007 Issue 35, p3868-3870. 3p.
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  Data: <searchLink fieldCode="DE" term="%22Silver+ions%22">Silver ions</searchLink><br /><searchLink fieldCode="DE" term="%22Silver+compounds%22">Silver compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Zinc%22">Zinc</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+crystallography%22">X-ray crystallography</searchLink>
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  Data: [Ag(UO2)3 (OAc)9][Zn(H2O)4(CH3CH2OH)2] (1, OAc = CH3COO−) crystallized from an ethanol solution and its structure was determined by IR spectroscopy, elemental analysis, 1H NMR, 13C NMR and X-ray crystallography; it is composed of [Zn(H2O)4(CH3CH2OH)2]2+ cations and [Ag(UO2)3(OAc)9]2− anions in which triuranyl [(UO2)(OAc)3]3 clusters are linked by the Ag ion. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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      – TitleFull: Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]: A novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ionsElectronic supplementary information (ESI) available: Tables of anisotropic thermal parameters, and bond distances and angles for 1. Polyhedral representation and schematic depiction of crystal packing of 1, IR spectrum, 1H NMR and 13C NMR, powder X-ray diffraction patterns, fluorescence emission spectra and excitation spectra. See DOI: 10.1039/b708799c
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