Facile Access to Pentavalent Uranium Organometallics: One-Electron Oxidation of Uranium(IV) Imido Complexes with Copper(l) Salts.

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Bibliographic Details
Title: Facile Access to Pentavalent Uranium Organometallics: One-Electron Oxidation of Uranium(IV) Imido Complexes with Copper(l) Salts.
Authors: Graves, Christopher R.1, Scott, Brian L.1, Morris, David E.1, Kiplinger, Jaqueline L.1 kiplinger@lanl.gov
Source: Journal of the American Chemical Society. 10/3/2007, Vol. 129 Issue 39, p11914-11915. 2p. 1 Graph.
Subjects: Migration of uranium, Organometallic compounds, Oxidation, Chemical processes, Actinide elements, Chemistry
Abstract: The article discusses the facile access of pentavalent uranium organometallic complexes. The electrochemical trends of oxidation procedure have found widespread application in different chemical processes. The roles of the 5f orbitals in metal structures, bonding and reactivity are intriguing in actinide chemistry.
Database: Engineering Source
Description
Abstract:The article discusses the facile access of pentavalent uranium organometallic complexes. The electrochemical trends of oxidation procedure have found widespread application in different chemical processes. The roles of the 5f orbitals in metal structures, bonding and reactivity are intriguing in actinide chemistry.
ISSN:00027863
DOI:10.1021/ja074889w