Synthesis and determination of the electron transfer numbers of alkynyl bridged multiferrocenyl derivatives

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Title: Synthesis and determination of the electron transfer numbers of alkynyl bridged multiferrocenyl derivatives
Authors: Han, Li-Min szj@imut.edu.cn, Suo, Quan-Ling1, Luo, Mei-hua1, Zhu, Ning1, Ma, Yan-Qiang1
Source: Inorganic Chemistry Communications. Aug2008, Vol. 11 Issue 8, p873-875. 3p.
Subjects: Electrochemical analysis, Quantitative chemical analysis, Electrochemistry, Conductometric analysis
Abstract: Abstract: Multiferrocenyl derivatives FcC(CH3)2Fc′–CFc(A) (Fc=C5H5FeC5H4, Fc′=C5H5FeC5H3) and FcC(CH3)2Fc′–CCFc′C(CH3)2Fc (B) have been synthesized and characterized by MS, NMR, FT-IR and elemental analysis. The molecular structure of compound A was given by single crystal X-ray diffraction. The electron transfer numbers of two compounds were determined by cyclic voltammetry and chronoamperomeric technique. [Copyright &y& Elsevier]
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Database: Engineering Source
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Abstract:Abstract: Multiferrocenyl derivatives FcC(CH3)2Fc′–CFc(A) (Fc=C5H5FeC5H4, Fc′=C5H5FeC5H3) and FcC(CH3)2Fc′–CCFc′C(CH3)2Fc (B) have been synthesized and characterized by MS, NMR, FT-IR and elemental analysis. The molecular structure of compound A was given by single crystal X-ray diffraction. The electron transfer numbers of two compounds were determined by cyclic voltammetry and chronoamperomeric technique. [Copyright &y& Elsevier]
ISSN:13877003
DOI:10.1016/j.inoche.2008.04.017