Bibliographic Details
| Title: |
Diastereoselective Synthesis of Carbapenams via Kinugasa Reaction. |
| Authors: |
Stecko, Sebastian1, Mames, Adam1, Furman, Bartłomiej1, Chmielewski, Marek1 chmiel@icho.edu.pl |
| Source: |
Journal of Organic Chemistry. 9/19/2008, Vol. 73 Issue 18, p7402-7404. 3p. 2 Charts. |
| Subjects: |
Ketones, Organic synthesis, Organocopper compounds, Cyclic compounds, Tartaric acid |
| Abstract: |
A facile approach to carbapenams via Kinugasa reaction between terminal copper acetylides and nonracemic cyclic nitrones derived from malic and tartaric acid is reported. The stereochemical preferences observed in these reactions are explained. The reaction provides an entry to the carbapenams basic skeleton. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
