General and Efficient Syntheses of C[sub 18]-4,8-Sphingadienines via S[sub N]2-Type Homoallylic...

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Title: General and Efficient Syntheses of C[sub 18]-4,8-Sphingadienines via S[sub N]2-Type Homoallylic...
Authors: Xiang-Zhu Wang, Yu-Lin Wu
Source: Journal of Organic Chemistry. 12/01/2000, Vol. 65 Issue 24, p8146. 6p. 17 Diagrams.
Subjects: Sphingolipids, Sphingosine
Abstract: Describes the stereoselective syntheses of C[sub 18]-4,8-sphingadiensis three and four as analogues of sphingosine one. Involvement of homoallylic coupling reactions mediated by thioether-stabilized copper reagents; Key steps in the syntheses performed.
Database: Engineering Source
Description
Abstract:Describes the stereoselective syntheses of C[sub 18]-4,8-sphingadiensis three and four as analogues of sphingosine one. Involvement of homoallylic coupling reactions mediated by thioether-stabilized copper reagents; Key steps in the syntheses performed.
ISSN:00223263
DOI:10.1021/jo005602f