Divergent Approach to a Large Variety of Versatile Luminescent Lanthanide Complexes.

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Title: Divergent Approach to a Large Variety of Versatile Luminescent Lanthanide Complexes.
Authors: Kadjane, Pascal1, Starck, Matthieu1, Camerel, Franck1, HilI, Diana2, HiIdebrandt, Niko3, Ziessel, Raymond1 ziessel@chimieu-strasbg.fr, Charbonniëre, Loïc J.1,4 charbonn@chimie.u-strasbg.fr
Source: Inorganic Chemistry. 6/1/2009, Vol. 48 Issue 11, p4601-4603. 3p. 1 Chart, 4 Graphs.
Subjects: Nucleophilic reactions, Rare earth metal compounds, Light beating spectroscopy, Absorption, Luminescence spectroscopy
Abstract: Using a regioselective strategy for nucleophilic aromatic substitution on polyfluoropyridines, a nonacoordinating precursor was designed that is adequately suited for complexation of lanthanide cations. Further functionalizations afforded numerous applications for near-IR emission, two-photon absorption spectroscopy, or the formation of luminescent gels. [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
Description
Abstract:Using a regioselective strategy for nucleophilic aromatic substitution on polyfluoropyridines, a nonacoordinating precursor was designed that is adequately suited for complexation of lanthanide cations. Further functionalizations afforded numerous applications for near-IR emission, two-photon absorption spectroscopy, or the formation of luminescent gels. [ABSTRACT FROM AUTHOR]
ISSN:00201669
DOI:10.1021/ic9001169