Enantioselective Syntheses of Monotetrahydrofuran Annonaceous Acetogenins Tonkinecin and....

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Bibliographic Details
Title: Enantioselective Syntheses of Monotetrahydrofuran Annonaceous Acetogenins Tonkinecin and....
Authors: Tai-Shan Hu, Qian Yu, Yu-Lin Wu, Yikang Wu
Source: Journal of Organic Chemistry. 02/09/2001, Vol. 66 Issue 3, p853. 9p. 8 Diagrams.
Subjects: Enantioselective catalysis, Tetrahydrofuran, Polyketides
Abstract: Investigates the enantioselective synthesis of monotetrahydrofuran acetogenins, tonkinecin and annonacin. Preparation of terminal acetylene from D-glucono-delta-lactone; Employment of asymmetric dihydroxylation as a common intermediate; Presence of boron trifluoride etherate in the coupling reaction.
Database: Engineering Source
Description
Abstract:Investigates the enantioselective synthesis of monotetrahydrofuran acetogenins, tonkinecin and annonacin. Preparation of terminal acetylene from D-glucono-delta-lactone; Employment of asymmetric dihydroxylation as a common intermediate; Presence of boron trifluoride etherate in the coupling reaction.
ISSN:00223263
DOI:10.1021/jo005643b