Bibliographic Details
| Title: |
The Elusive 16-Electron Cp*M(NO)Me[sub 2] (M = Mo, W) Complexes and Their Spontaneous... |
| Authors: |
Sharp, W. Brett, Daff, P. James, McNeil, W. Stephen, Legzdins, Peter |
| Source: |
Journal of the American Chemical Society. 7/4/2001, Vol. 123 Issue 26, p6272. 11p. 16 Diagrams, 1 Graph. |
| Subjects: |
Complex compounds, Metathesis reactions, Solvents |
| Abstract: |
Investigates the influence of ethereal solvents upon the course of the reaction of [Cp*Mo(NO)Cl(mu-Cl)][sub 2] with methyllithium. Metathesis reactions of [Cp*Mo(NO)Cl(mu-Cl)][sub 2] with magnesium reagents, methyllithium in ether solvents and methyllithium in toluene; Solid-state structure of Cp*Mo(NO)Me[sub 2]; Mechanism of isomerization of dimethyl complexes. |
| Database: |
Engineering Source |
