The Elusive 16-Electron Cp*M(NO)Me[sub 2] (M = Mo, W) Complexes and Their Spontaneous...

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Title: The Elusive 16-Electron Cp*M(NO)Me[sub 2] (M = Mo, W) Complexes and Their Spontaneous...
Authors: Sharp, W. Brett, Daff, P. James, McNeil, W. Stephen, Legzdins, Peter
Source: Journal of the American Chemical Society. 7/4/2001, Vol. 123 Issue 26, p6272. 11p. 16 Diagrams, 1 Graph.
Subjects: Complex compounds, Metathesis reactions, Solvents
Abstract: Investigates the influence of ethereal solvents upon the course of the reaction of [Cp*Mo(NO)Cl(mu-Cl)][sub 2] with methyllithium. Metathesis reactions of [Cp*Mo(NO)Cl(mu-Cl)][sub 2] with magnesium reagents, methyllithium in ether solvents and methyllithium in toluene; Solid-state structure of Cp*Mo(NO)Me[sub 2]; Mechanism of isomerization of dimethyl complexes.
Database: Engineering Source
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DbLabel: Engineering Source
An: 5036137
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  Data: The Elusive 16-Electron Cp*M(NO)Me[sub 2] (M = Mo, W) Complexes and Their Spontaneous...
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  Data: <searchLink fieldCode="JN" term="%22Journal+of+the+American+Chemical+Society%22">Journal of the American Chemical Society</searchLink>. 7/4/2001, Vol. 123 Issue 26, p6272. 11p. 16 Diagrams, 1 Graph.
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  Data: <searchLink fieldCode="DE" term="%22Complex+compounds%22">Complex compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Metathesis+reactions%22">Metathesis reactions</searchLink><br /><searchLink fieldCode="DE" term="%22Solvents%22">Solvents</searchLink>
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  Data: Investigates the influence of ethereal solvents upon the course of the reaction of [Cp*Mo(NO)Cl(mu-Cl)][sub 2] with methyllithium. Metathesis reactions of [Cp*Mo(NO)Cl(mu-Cl)][sub 2] with magnesium reagents, methyllithium in ether solvents and methyllithium in toluene; Solid-state structure of Cp*Mo(NO)Me[sub 2]; Mechanism of isomerization of dimethyl complexes.
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        Value: 10.1021/ja002856+
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      – Code: eng
        Text: English
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        PageCount: 11
        StartPage: 6272
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      – SubjectFull: Complex compounds
        Type: general
      – SubjectFull: Metathesis reactions
        Type: general
      – SubjectFull: Solvents
        Type: general
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      – TitleFull: The Elusive 16-Electron Cp*M(NO)Me[sub 2] (M = Mo, W) Complexes and Their Spontaneous...
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            NameFull: Sharp, W. Brett
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            NameFull: Daff, P. James
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            NameFull: McNeil, W. Stephen
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            NameFull: Legzdins, Peter
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              Text: 7/4/2001
              Type: published
              Y: 2001
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