Synthesis of the 6-deoxytalose-containing tri- and hexasaccharides of the O-antigen polysaccharide from Mesorhizobium huakuii IFO15243T

Saved in:
Bibliographic Details
Title: Synthesis of the 6-deoxytalose-containing tri- and hexasaccharides of the O-antigen polysaccharide from Mesorhizobium huakuii IFO15243T
Authors: Zong, Guanghui1, Feng, Yichen1, Liang, Xiaomei1, Chen, Liezhong2, Zhang, Jianjun1 zhangjianjun@cau.edu.cn, Wang, Daoquan1
Source: Carbohydrate Research. Sep2010, Vol. 345 Issue 14, p2067-2073. 7p.
Subjects: Oligosaccharides, Organic synthesis, Antigens, Polysaccharides, Bacteria, Glycosylation, Monomers, Glycoconjugates
Abstract: Abstract: The synthesis of a trisaccharide and a hexasaccharide, the monomer and dimer of the repeating unit of O-antigen polysaccharide from Mesorhizobium huakuii IFO15243, has been accomplished through suitable protecting group manipulations and stereoselective glycosylation reactions starting from commercially available l-rhamnose. The target oligosaccharides in the form of their p-methoxyphenyl glycosides are suitable for further glycoconjugate formation via selective cleavage of this group. [ABSTRACT FROM AUTHOR]
Copyright of Carbohydrate Research is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
Description
Abstract:Abstract: The synthesis of a trisaccharide and a hexasaccharide, the monomer and dimer of the repeating unit of O-antigen polysaccharide from Mesorhizobium huakuii IFO15243, has been accomplished through suitable protecting group manipulations and stereoselective glycosylation reactions starting from commercially available l-rhamnose. The target oligosaccharides in the form of their p-methoxyphenyl glycosides are suitable for further glycoconjugate formation via selective cleavage of this group. [ABSTRACT FROM AUTHOR]
ISSN:00086215
DOI:10.1016/j.carres.2010.07.023