Bibliographic Details
| Title: |
Tetranuclear copper(i) carboxylates: the effect of a stepwise increase in Lewis acidity on solid-state structures and photoluminescenceElectronic supplementary information (ESI) available: IR, X-ray powder diffraction details, additional thermal ellipsoid plots of the structures. CCDC reference numbers 817555–817557. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt10848d |
| Authors: |
Oleksandr Hietsoi1, Alexander S. Filatov1, Cristina Dubceac1, Marina A. Petrukhina1 |
| Source: |
Dalton Transactions: An International Journal of Inorganic Chemistry. Aug2011, Vol. 40 Issue 34, p8598-8603. 6p. |
| Subjects: |
Organocopper compounds, Carboxylic acids, Lewis acids, Aliphatic compounds, X-ray diffraction, Solid state chemistry, Photoluminescence, Molecular structure |
| Abstract: |
X-Ray diffraction studies of three aliphatic copper(i) carboxylates revealed a tetranuclear core structure for [Cu4(O2CCH2CH3)4] (1), [Cu4(O2CCF3)(O2CCH2CH3)3] (2), and [Cu4(O2CCF2CF3)4] (3). The effect of a stepwise increase in electrophilicity on solid-state interactions of copper(i) tetramers as well as the implications of structural variations on photoluminescent properties of the above copper(i) propionates have been discussed. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
