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Tetranuclear copper(i) carboxylates: the effect of a stepwise increase in Lewis acidity on solid-state structures and photoluminescenceElectronic supplementary information (ESI) available: IR, X-ray powder diffraction details, additional thermal ellipsoid plots of the structures. CCDC reference numbers 817555–817557. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt10848d

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Title: Tetranuclear copper(i) carboxylates: the effect of a stepwise increase in Lewis acidity on solid-state structures and photoluminescenceElectronic supplementary information (ESI) available: IR, X-ray powder diffraction details, additional thermal ellipsoid plots of the structures. CCDC reference numbers 817555–817557. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt10848d
Authors: Oleksandr Hietsoi1, Alexander S. Filatov1, Cristina Dubceac1, Marina A. Petrukhina1
Source: Dalton Transactions: An International Journal of Inorganic Chemistry. Aug2011, Vol. 40 Issue 34, p8598-8603. 6p.
Subjects: Organocopper compounds, Carboxylic acids, Lewis acids, Aliphatic compounds, X-ray diffraction, Solid state chemistry, Photoluminescence, Molecular structure
Abstract: X-Ray diffraction studies of three aliphatic copper(i) carboxylates revealed a tetranuclear core structure for [Cu4(O2CCH2CH3)4] (1), [Cu4(O2CCF3)(O2CCH2CH3)3] (2), and [Cu4(O2CCF2CF3)4] (3). The effect of a stepwise increase in electrophilicity on solid-state interactions of copper(i) tetramers as well as the implications of structural variations on photoluminescent properties of the above copper(i) propionates have been discussed. [ABSTRACT FROM AUTHOR]
Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: Tetranuclear copper(i) carboxylates: the effect of a stepwise increase in Lewis acidity on solid-state structures and photoluminescenceElectronic supplementary information (ESI) available: IR, X-ray powder diffraction details, additional thermal ellipsoid plots of the structures. CCDC reference numbers 817555–817557. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt10848d
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  Data: <searchLink fieldCode="JN" term="%22Dalton+Transactions%3A+An+International+Journal+of+Inorganic+Chemistry%22">Dalton Transactions: An International Journal of Inorganic Chemistry</searchLink>. Aug2011, Vol. 40 Issue 34, p8598-8603. 6p.
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  Data: <searchLink fieldCode="DE" term="%22Organocopper+compounds%22">Organocopper compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Carboxylic+acids%22">Carboxylic acids</searchLink><br /><searchLink fieldCode="DE" term="%22Lewis+acids%22">Lewis acids</searchLink><br /><searchLink fieldCode="DE" term="%22Aliphatic+compounds%22">Aliphatic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+diffraction%22">X-ray diffraction</searchLink><br /><searchLink fieldCode="DE" term="%22Solid+state+chemistry%22">Solid state chemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Photoluminescence%22">Photoluminescence</searchLink><br /><searchLink fieldCode="DE" term="%22Molecular+structure%22">Molecular structure</searchLink>
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  Data: X-Ray diffraction studies of three aliphatic copper(i) carboxylates revealed a tetranuclear core structure for [Cu4(O2CCH2CH3)4] (1), [Cu4(O2CCF3)(O2CCH2CH3)3] (2), and [Cu4(O2CCF2CF3)4] (3). The effect of a stepwise increase in electrophilicity on solid-state interactions of copper(i) tetramers as well as the implications of structural variations on photoluminescent properties of the above copper(i) propionates have been discussed. [ABSTRACT FROM AUTHOR]
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  Data: <i>Copyright of Dalton Transactions: An International Journal of Inorganic Chemistry is the property of Royal Society of Chemistry and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1039/c1dt10848d
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        Text: English
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      – SubjectFull: Organocopper compounds
        Type: general
      – SubjectFull: Carboxylic acids
        Type: general
      – SubjectFull: Lewis acids
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      – SubjectFull: Aliphatic compounds
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      – SubjectFull: Solid state chemistry
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      – SubjectFull: Photoluminescence
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      – SubjectFull: Molecular structure
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      – TitleFull: Tetranuclear copper(i) carboxylates: the effect of a stepwise increase in Lewis acidity on solid-state structures and photoluminescenceElectronic supplementary information (ESI) available: IR, X-ray powder diffraction details, additional thermal ellipsoid plots of the structures. CCDC reference numbers 817555–817557. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt10848d
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            NameFull: Alexander S. Filatov
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              Text: Aug2011
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