Bibliographic Details
| Title: |
Effect of oxygenation time on signal of a sensor based on ionic liquids |
| Authors: |
Gębicki, Jacek1 jacek.gebicki@pg.gda.pl, Kloskowski, Adam2, Chrzanowski, Wojciech2 |
| Source: |
Electrochimica Acta. Nov2011, Vol. 56 Issue 27, p9910-9915. 6p. |
| Subjects: |
Ionic liquids, Oxygen, Chemical detectors, Electrodes, Volumetric analysis, Analytical chemistry, Oxidation-reduction reaction, Reaction mechanisms (Chemistry) |
| Abstract: |
Abstract: The paper presents an oxygen sensor based on ionic liquids and solid electrodes. The following ionic liquids have been employed: [BMIM][BF4], [HMIM][Cl], [BMIM][N(CN2)]. Minimum time of the sensor exposure to analyte, after which the signal (current intensity) was stable, has been evaluated. An impact of volumetric flow rate of analyte on the sensor exposure time and signal has been determined. A product of permeability coefficient and solubility of oxygen in ionic liquids has been estimated. A mechanism of oxygen reduction on a surface of the solid electrodes, in the ionic liquid environment has been presented. Overall cathodic coefficients of transition for the sensors with particular ionic liquids have been determined as a function of potential scan rate. [Copyright &y& Elsevier] |
|
Copyright of Electrochimica Acta is the property of Pergamon Press - An Imprint of Elsevier Science and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.) |
| Database: |
Engineering Source |
