Copper(II)-mediated in-situ hydrolyses of pyrroline N-oxide and benzonitrile leading to a mixed ligand complex

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Title: Copper(II)-mediated in-situ hydrolyses of pyrroline N-oxide and benzonitrile leading to a mixed ligand complex
Authors: Lasri, Jamal1 jamal.lasri@ist.utl.pt, Gupta, Samik1, da Silva, M. Fátima C. Guedes1,2 fatima.guedes@ist.utl.pt, Pombeiro, Armando J.L.1 pombeiro@ist.utl.pt
Source: Inorganic Chemistry Communications. Apr2012, Vol. 18, p69-72. 4p.
Subjects: Copper compounds, Hydrolysis, Benzonitrile, Pyrrolidine, Ligands (Chemistry), X-ray crystallography
Abstract: Abstract: Copper(II)-mediated in-situ hydrolyses of 5,5-dimethyl-1-pyrroline N-oxide into 5,5-dimethyl-2-oxo-pyrrolidine-1-olate (L1), and of benzonitrile into benzamide, are observed in the formation of complex [Cu(L1)2(C6H5C(═O)NH2)] (1), which has been characterized by IR, elemental analysis and X-ray diffraction crystallography. [Copyright &y& Elsevier]
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Abstract:Abstract: Copper(II)-mediated in-situ hydrolyses of 5,5-dimethyl-1-pyrroline N-oxide into 5,5-dimethyl-2-oxo-pyrrolidine-1-olate (L1), and of benzonitrile into benzamide, are observed in the formation of complex [Cu(L1)2(C6H5C(═O)NH2)] (1), which has been characterized by IR, elemental analysis and X-ray diffraction crystallography. [Copyright &y& Elsevier]
ISSN:13877003
DOI:10.1016/j.inoche.2012.01.012