Copper(II)-mediated in-situ hydrolyses of pyrroline N-oxide and benzonitrile leading to a mixed ligand complex

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Title: Copper(II)-mediated in-situ hydrolyses of pyrroline N-oxide and benzonitrile leading to a mixed ligand complex
Authors: Lasri, Jamal1 jamal.lasri@ist.utl.pt, Gupta, Samik1, da Silva, M. Fátima C. Guedes1,2 fatima.guedes@ist.utl.pt, Pombeiro, Armando J.L.1 pombeiro@ist.utl.pt
Source: Inorganic Chemistry Communications. Apr2012, Vol. 18, p69-72. 4p.
Subjects: Copper compounds, Hydrolysis, Benzonitrile, Pyrrolidine, Ligands (Chemistry), X-ray crystallography
Abstract: Abstract: Copper(II)-mediated in-situ hydrolyses of 5,5-dimethyl-1-pyrroline N-oxide into 5,5-dimethyl-2-oxo-pyrrolidine-1-olate (L1), and of benzonitrile into benzamide, are observed in the formation of complex [Cu(L1)2(C6H5C(═O)NH2)] (1), which has been characterized by IR, elemental analysis and X-ray diffraction crystallography. [Copyright &y& Elsevier]
Copyright of Inorganic Chemistry Communications is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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  Data: <searchLink fieldCode="JN" term="%22Inorganic+Chemistry+Communications%22">Inorganic Chemistry Communications</searchLink>. Apr2012, Vol. 18, p69-72. 4p.
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  Data: <searchLink fieldCode="DE" term="%22Copper+compounds%22">Copper compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Hydrolysis%22">Hydrolysis</searchLink><br /><searchLink fieldCode="DE" term="%22Benzonitrile%22">Benzonitrile</searchLink><br /><searchLink fieldCode="DE" term="%22Pyrrolidine%22">Pyrrolidine</searchLink><br /><searchLink fieldCode="DE" term="%22Ligands+%28Chemistry%29%22">Ligands (Chemistry)</searchLink><br /><searchLink fieldCode="DE" term="%22X-ray+crystallography%22">X-ray crystallography</searchLink>
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  Data: Abstract: Copper(II)-mediated in-situ hydrolyses of 5,5-dimethyl-1-pyrroline N-oxide into 5,5-dimethyl-2-oxo-pyrrolidine-1-olate (L1), and of benzonitrile into benzamide, are observed in the formation of complex [Cu(L1)2(C6H5C(═O)NH2)] (1), which has been characterized by IR, elemental analysis and X-ray diffraction crystallography. [Copyright &y& Elsevier]
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  Data: <i>Copyright of Inorganic Chemistry Communications is the property of Elsevier B.V. and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
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        Value: 10.1016/j.inoche.2012.01.012
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        Text: English
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      – SubjectFull: Benzonitrile
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      – SubjectFull: Pyrrolidine
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              Text: Apr2012
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