Bibliographic Details
| Title: |
Characterization of La0.995Ca0.005NbO4/Ni anode functional layer by electrophoretic deposition in a La0.995Ca0.005NbO4 electrolyte based PCFC |
| Authors: |
Bozza, F.1 frbo@risoe.dtu.dk, Schafbauer, W.2, Meulenberg, W.A.2, Bonanos, N.1 |
| Source: |
International Journal of Hydrogen Energy. May2012, Vol. 37 Issue 9, p8027-8032. 6p. |
| Subjects: |
Lanthanum compounds, Anodes, Nickel electrodes, Electrophoretic deposition, Electrolytes, Sintering, Performance evaluation |
| Abstract: |
Abstract: The Electrophoretic Deposition (EPD) technique has been applied to the preparation of a porous La0.995Ca0.005NbO4/Ni composite anode layer, deposited on a porous pre-sintered La0.995Ca0.005NbO4/Ni support. Powders of La0.995Ca0.005NbO4 and NiO were suspended in a solution of acetylacetone, iodine and water. Selectivity in the composition of the deposited layer was analyzed as a function of the suspension compositions and deposition conditions. A quasi-symmetrical cell was produced by depositing La0.995Ca0.005NbO4 electrolyte layer on the anode layer by EPD, and by applying a porous La0.995Ca0.005NbO4/Ni counter electrode on the dense electrolyte layer by brushing. The performance of the electrodes was evaluated by electrochemical impedance spectroscopy in 3% wet H2. [Copyright &y& Elsevier] |
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| Database: |
Engineering Source |