View in EDS

Zur Elektronenstruktur metallorganischer Komplexe der f-Elemente 39. Experimentelle Erfassung und Simulation des Kristallfeld-Aufspaltungsmusters von (eta8-Cyclooctatetraenyl)[hydrotris(3,5-dimethylpyrazol-1-yl)borato]-praseodym(III){(COT)Pr[HB(Me2pz)3]}.

Saved in:
Bibliographic Details
Title: Zur Elektronenstruktur metallorganischer Komplexe der f-Elemente 39. Experimentelle Erfassung und Simulation des Kristallfeld-Aufspaltungsmusters von (eta8-Cyclooctatetraenyl)[hydrotris(3,5-dimethylpyrazol-1-yl)borato]-praseodym(III){(COT)Pr[HB(Me2pz)3]}.
Authors: Amberger, Von H.-D., Jank, S., Reddmann, H., Edelmann, F. T.
Source: Molecular Physics. 8/20/96, Vol. 88 Issue 6, p1439-1458. 20p.
Subjects: Organometallic compounds, Magnetochemistry, Magnetooptics
Abstract: The magnetochemical, optical and magnetooptical properties of (COT)- Pr[HB(Me2pz)3] have been determined at ambient and low temperatures. First, the absorption and luminescence spectra indicate that the f electrons experience a dominant crystal field (CF) of C8v symmetry and a slight perturbation field of trigonal symmetry (which mainly may be studied by the CF parameter B66). On the basis of the optical spectra the underlying CF splitting pattern is derived, and simulated by fitting the free parameters of an empirical Hamiltonian. For 35 assignments an RMS deviation of 28 cm-1 is achieved. The parameters obtained are discussed and compared with the predictions of previous model calculations. [ABSTRACT FROM AUTHOR]
Copyright of Molecular Physics is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
Database: Engineering Source
FullText Text:
  Availability: 0
Header DbId: egs
DbLabel: Engineering Source
An: 7612976
AccessLevel: 6
PubType: Academic Journal
PubTypeId: academicJournal
PreciseRelevancyScore: 0
IllustrationInfo
Items – Name: Title
  Label: Title
  Group: Ti
  Data: Zur Elektronenstruktur metallorganischer Komplexe der f-Elemente 39. Experimentelle Erfassung und Simulation des Kristallfeld-Aufspaltungsmusters von (eta8-Cyclooctatetraenyl)[hydrotris(3,5-dimethylpyrazol-1-yl)borato]-praseodym(III){(COT)Pr[HB(Me2pz)3]}.
– Name: Author
  Label: Authors
  Group: Au
  Data: <searchLink fieldCode="AR" term="%22Amberger%2C+Von+H%2E-D%2E%22">Amberger, Von H.-D.</searchLink><br /><searchLink fieldCode="AR" term="%22Jank%2C+S%2E%22">Jank, S.</searchLink><br /><searchLink fieldCode="AR" term="%22Reddmann%2C+H%2E%22">Reddmann, H.</searchLink><br /><searchLink fieldCode="AR" term="%22Edelmann%2C+F%2E+T%2E%22">Edelmann, F. T.</searchLink>
– Name: TitleSource
  Label: Source
  Group: Src
  Data: <searchLink fieldCode="JN" term="%22Molecular+Physics%22">Molecular Physics</searchLink>. 8/20/96, Vol. 88 Issue 6, p1439-1458. 20p.
– Name: Subject
  Label: Subjects
  Group: Su
  Data: <searchLink fieldCode="DE" term="%22Organometallic+compounds%22">Organometallic compounds</searchLink><br /><searchLink fieldCode="DE" term="%22Magnetochemistry%22">Magnetochemistry</searchLink><br /><searchLink fieldCode="DE" term="%22Magnetooptics%22">Magnetooptics</searchLink>
– Name: Abstract
  Label: Abstract
  Group: Ab
  Data: The magnetochemical, optical and magnetooptical properties of (COT)- Pr[HB(Me2pz)3] have been determined at ambient and low temperatures. First, the absorption and luminescence spectra indicate that the f electrons experience a dominant crystal field (CF) of C8v symmetry and a slight perturbation field of trigonal symmetry (which mainly may be studied by the CF parameter B66). On the basis of the optical spectra the underlying CF splitting pattern is derived, and simulated by fitting the free parameters of an empirical Hamiltonian. For 35 assignments an RMS deviation of 28 cm-1 is achieved. The parameters obtained are discussed and compared with the predictions of previous model calculations. [ABSTRACT FROM AUTHOR]
– Name: AbstractSuppliedCopyright
  Label:
  Group: Ab
  Data: <i>Copyright of Molecular Physics is the property of Taylor & Francis Ltd and its content may not be copied or emailed to multiple sites without the copyright holder's express written permission. Additionally, content may not be used with any artificial intelligence tools or machine learning technologies. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract.</i> (Copyright applies to all Abstracts.)
PLink https://search.ebscohost.com/login.aspx?direct=true&site=eds-live&db=egs&AN=7612976
RecordInfo BibRecord:
  BibEntity:
    Identifiers:
      – Type: doi
        Value: 10.1080/00268979650025542
    Languages:
      – Code: eng
        Text: English
    PhysicalDescription:
      Pagination:
        PageCount: 20
        StartPage: 1439
    Subjects:
      – SubjectFull: Organometallic compounds
        Type: general
      – SubjectFull: Magnetochemistry
        Type: general
      – SubjectFull: Magnetooptics
        Type: general
    Titles:
      – TitleFull: Zur Elektronenstruktur metallorganischer Komplexe der f-Elemente 39. Experimentelle Erfassung und Simulation des Kristallfeld-Aufspaltungsmusters von (eta8-Cyclooctatetraenyl)[hydrotris(3,5-dimethylpyrazol-1-yl)borato]-praseodym(III){(COT)Pr[HB(Me2pz)3]}.
        Type: main
  BibRelationships:
    HasContributorRelationships:
      – PersonEntity:
          Name:
            NameFull: Amberger, Von H.-D.
      – PersonEntity:
          Name:
            NameFull: Jank, S.
      – PersonEntity:
          Name:
            NameFull: Reddmann, H.
      – PersonEntity:
          Name:
            NameFull: Edelmann, F. T.
    IsPartOfRelationships:
      – BibEntity:
          Dates:
            – D: 20
              M: 08
              Text: 8/20/96
              Type: published
              Y: 1996
          Identifiers:
            – Type: issn-print
              Value: 00268976
          Numbering:
            – Type: volume
              Value: 88
            – Type: issue
              Value: 6
          Titles:
            – TitleFull: Molecular Physics
              Type: main
ResultId 1