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Leaching of Biocides from Façades under Natural Weather Conditions.

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Title: Leaching of Biocides from Façades under Natural Weather Conditions.
Authors: Burkhardt, M.1,2 Michael.Burkhardt@hsr.ch, Zuleeg, S.1,3, Vonbank, R.4, Bester, K.5, Carmeliet, J.4,6, Boller, M.1, Wangler, T.4,6
Source: Environmental Science & Technology. 5/15/2012, Vol. 46 Issue 10, p5497-5503. 7p.
Subjects: Biocides, Leaching & the environment, Mass budget (Geophysics), Field emission, Diuron, Isoproturon
Abstract: Biocides are included in organic building façade coatings as protection against biological attack by algae and fungi but have the potential to enter the environment via leaching into runoff from wind driven rain. The following field study correlates wind driven rain to runoff and measured the release of several commonly used organic biocides (terbutryn, Irgarol 1051, diuron, isoproturon, OIT, DCOIT) in organic façade coatings from four coating systems. During one year of exposure of a west oriented model house façade in the Zurich, Switzerland area, an average of 62.7 L/m², or 6.3% of annual precipitation came off the four façade panels installed as runoff. The ISO method for calculating wind driven rain loads is adapted to predict runoff and can be used in the calculation of emissions in the field. Biocide concentrations tend to be higher in the early lifetime of the coatings and then reach fairly consistent levels later, generally ranging on the order of mg/L or hundreds of μg/L. On the basis of the amount remaining in the film after exposure, the occurrence of transformation products, and the calculated amounts in the leachate, degradation plays a significant role in the overall mass balance. [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
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Abstract:Biocides are included in organic building façade coatings as protection against biological attack by algae and fungi but have the potential to enter the environment via leaching into runoff from wind driven rain. The following field study correlates wind driven rain to runoff and measured the release of several commonly used organic biocides (terbutryn, Irgarol 1051, diuron, isoproturon, OIT, DCOIT) in organic façade coatings from four coating systems. During one year of exposure of a west oriented model house façade in the Zurich, Switzerland area, an average of 62.7 L/m², or 6.3% of annual precipitation came off the four façade panels installed as runoff. The ISO method for calculating wind driven rain loads is adapted to predict runoff and can be used in the calculation of emissions in the field. Biocide concentrations tend to be higher in the early lifetime of the coatings and then reach fairly consistent levels later, generally ranging on the order of mg/L or hundreds of μg/L. On the basis of the amount remaining in the film after exposure, the occurrence of transformation products, and the calculated amounts in the leachate, degradation plays a significant role in the overall mass balance. [ABSTRACT FROM AUTHOR]
ISSN:0013936X
DOI:10.1021/es2040009