Bibliographic Details
| Title: |
Water-Insoluble Heterometal-Oxide-Based PhotocatalystsEffective for the Photo-Decomposition of Methyl Orange. |
| Authors: |
Chen, Yong-Qiang1, Li, Guo-Rong1, Qu, Yang-Kun1, Zhang, Ying-Hui1, He, Kun-Huan1, Gao, Qiang1, Bu, Xian-He1 |
| Source: |
Crystal Growth & Design. Feb2013, Vol. 13 Issue 2, p901-907. 7p. |
| Subjects: |
Water chemistry, Metallic oxides, Photocatalysis, Chemical decomposition, Methyl groups, Metal ions |
| Abstract: |
Two water-insoluble isostructural inorganic–organichybridmaterials, [M(pytpy)2Mo4O13]∞(M = Cu 1, Ni 2, pytpy =4′-(4-pyridyl)-4,2′:6′,4″-terpyridine),have been prepared by in situformation of the Mo4O132–clusters from the decompositionof H3PMo12under hydrothermal conditions. Bothof the two complexes display three-dimensional (3D) “pillar-layer”frameworks based on bimetal-oxide layers pillared by the pytpy ligands.Topological analysis revealed that two 3D frameworks can be simplifiedinto (3,4,4)-connected (42.62.83)2(4.62)2(44.102) and (3,5,6)-connected (42.6)2(44.66)2(44.68.83) topologies with the metal ions as nodes, respectively. Importantly,good photocatalytic activities were observed for both complexes inthe photodecomposition of methyl orange (MO) solution under UV lightirradiation. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |
