Bibliographic Details
| Title: |
Why is the CO2–CS2 non-ideality larger than in CO2–CCl4? A Raman scattering study. |
| Authors: |
Besnard, M.1 m.besnard@ism.u-bordeaux1.fr, Cabaço, M.I.2, Coutinho, J.A.P.3, Danten, Y.1 |
| Source: |
Chemical Physics Letters. Sep2013, Vol. 583, p49-53. 5p. |
| Subjects: |
Carbon dioxide, Carbon disulfide, Raman scattering, Mixtures, Liquid-liquid interfaces, Low temperatures |
| Abstract: |
Highlights: [•] Raman spectroscopic study of CO2–CCl4 and CO2–CS2 mixtures at 313K. [•] CO2–CCl4 is found almost ideal and CO2–CS2 strongly non-ideal. [•] Nano-segregation without demixing in CS2 concentrated mixtures. [•] A diversity of species are present in CO2 concentrated mixtures. [•] The connection with the liquid–liquid demixing at lower temperature is discussed. [ABSTRACT FROM AUTHOR] |
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| Database: |
Engineering Source |