Imidazolium-based ionic liquid-type surfactant as pseudostationary phase in micellar electrokinetic chromatography of highly hydrophilic urinary nucleosides.

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Bibliographic Details
Title: Imidazolium-based ionic liquid-type surfactant as pseudostationary phase in micellar electrokinetic chromatography of highly hydrophilic urinary nucleosides.
Authors: Rageh, Azza H.1, Pyell, Ute1 pyellu@staff.uni-marburg.de
Source: Journal of Chromatography A. Nov2013, Vol. 1316, p135-146. 12p.
Subjects: Imidazoles, Ionic liquids, Cationic surfactants, Stationary phase (Chromatography), Micellar electrokinetic chromatography, Nucleosides, Urinalysis
Abstract: Highlights: [•] Imidazolium-based IL shows higher reproducibility relative to alternative cationic surfactant. [•] Selective and fast separation of urinary nucleosides is achieved using C14MImBr. [•] Borate complexation is a precondition for interaction of nucleosides with C14MImBr. [•] Electrostatic attraction is the main mode of interaction with C14MImBr micelles. [•] Retention factors can be regulated by variation of competing ion concentration. [ABSTRACT FROM AUTHOR]
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Database: Engineering Source
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Abstract:Highlights: [•] Imidazolium-based IL shows higher reproducibility relative to alternative cationic surfactant. [•] Selective and fast separation of urinary nucleosides is achieved using C14MImBr. [•] Borate complexation is a precondition for interaction of nucleosides with C14MImBr. [•] Electrostatic attraction is the main mode of interaction with C14MImBr micelles. [•] Retention factors can be regulated by variation of competing ion concentration. [ABSTRACT FROM AUTHOR]
ISSN:00219673
DOI:10.1016/j.chroma.2013.09.079