Bibliographic Details
| Title: |
Asymmetric formation of quaternary centers through aza-annulation of chiral beta-enamino esters... |
| Authors: |
Barta, Nancy S., Brode, Adam |
| Source: |
Journal of the American Chemical Society. 7/13/94, Vol. 116 Issue 14, p6201. 6p. 3 Diagrams, 3 Charts. |
| Subjects: |
Chirality, Stereochemistry |
| Abstract: |
Discusses the stereoselective formation of quaternary carbon centers through the aza-annulation of beta-enamino ester substrates with acrylate derivatives. Generation of tetrasubstituted secondary enamines from the optically active primary amine (R)-alpha-phenethylamine and the alpha-amino esters of L-valine and (R)-phenylglycine. |
| Database: |
Engineering Source |